{"entities":{"Q2590132":{"pageid":2600875,"ns":120,"title":"Item:Q2590132","lastrevid":44426859,"modified":"2025-11-22T20:46:20Z","type":"item","id":"Q2590132","labels":{"en":{"language":"en","value":"The characteristics of thermal diffusion."}},"descriptions":{"en":{"language":"en","value":"scientific article; zbMATH DE number 2509555"}},"aliases":{},"claims":{"P31":[{"mainsnak":{"snaktype":"value","property":"P31","hash":"fd5912e4dab4b881a8eb0eb27e7893fef55176ad","datavalue":{"value":{"entity-type":"item","numeric-id":56887,"id":"Q56887"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2590132$77229F87-CBB2-4D68-B897-B7518BB60E47","rank":"normal"}],"P159":[{"mainsnak":{"snaktype":"value","property":"P159","hash":"3c872a2c3c06f100ec612abe60afdc6e4c415b50","datavalue":{"value":{"text":"The characteristics of thermal diffusion.","language":"en"},"type":"monolingualtext"},"datatype":"monolingualtext"},"type":"statement","id":"Q2590132$7BFB0E62-DCD3-4957-B85F-FA6C1345A742","rank":"normal"}],"P225":[{"mainsnak":{"snaktype":"value","property":"P225","hash":"faae15d59be2e3d3133e63611465a29c77069994","datavalue":{"value":"66.1417.02","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2590132$D74D28FC-979A-4578-990C-EF14ED38D251","rank":"normal"}],"P16":[{"mainsnak":{"snaktype":"value","property":"P16","hash":"6961484cda12835d888855553686d985feee633b","datavalue":{"value":{"entity-type":"item","numeric-id":570540,"id":"Q570540"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2590132$62F7F473-FF23-4149-87BB-911010297476","rank":"normal"}],"P28":[{"mainsnak":{"snaktype":"value","property":"P28","hash":"1701512ca85d58575d88b06da5ab938c2d9a4cd9","datavalue":{"value":{"time":"+1940-00-00T00:00:00Z","timezone":0,"before":0,"after":0,"precision":9,"calendarmodel":"http://www.wikidata.org/entity/Q1985727"},"type":"time"},"datatype":"time"},"type":"statement","id":"Q2590132$687EF5C0-56BC-4052-A3CB-8AF8265D2155","rank":"normal"}],"P1448":[{"mainsnak":{"snaktype":"value","property":"P1448","hash":"f3881a6356de80e2326cb77437f9c3390828288f","datavalue":{"value":"Der Diffusionsstrom in einem bin\u00e4ren Gasgemisch (\\(c_{1,2}\\) Relativkonzentrationen), ist \\(-ND_{12}(\\operatorname{grad} c_1 + \\alpha c_1c_2\\operatorname{grad}\\ln T)\\). Der Thermodiffusionsfaktor \\(\\alpha\\) kann in erster N\u00e4herung bei beliebigem, zwischenmolekularem Kraftgesetz in der Form  \\[  \\alpha = 5(C - 1) g \\text{\\;mit\\;} g = (c_1Q_1g_1 + c_2Q_2g_2) (c_1^2Q_1 + c_1c_2Q_{12} + c_2^2Q_2)^{-1},  \\]  dargestellt werden. Dieser Ausdruck wird eingehend diskutiert im Hinblick auf Deutung und Anregung von Experimenten. \\(C\\) h\u00e4ngt nur von der Temperatur und dem Kraftgesetz zwischen verschiedenen Molekeln ab. \\(Q_{1,2}\\), \\(Q_{12}\\) und \\(g_{1,2}\\) sind Funk\\-tionen der relativen Massendifferenz \\(M = (M_1 - M_2) (M_1 + M_2)^{-1}\\) sowie gewisser, weiterer Zahlenwerte \\(A\\), \\(B\\), \\(x_{12}\\), \\(x_{21}\\), welche auch noch vom Kraftgesetz zwischen gleichen Molekeln abh\u00e4ngen. \\(x_{12}\\), \\(x_{21}\\) lassen sich durch \\(A\\) und die Verh\u00e4ltnisse \\(\\mu_1/D_{12}\\), \\(\\mu_2/D_{12}\\) ausdr\u00fccken, wo \\(\\mu_{1,2}\\) die Reibungskoeffizienten der reinen Gase sind. Die Abh\u00e4ngigkeit des \\(\\alpha\\) von \\(c_{1,2}\\) kann allgemein diskutiert werden. Es ist m\u00f6glieh, da\u00df \\(\\alpha\\) sein Vorzeichen umkehrt zwischen \\(c_1 = 0\\) und \\(c_1 = 1\\). F\u00fcr den speziellen Fall, da\u00df die zwischenmolekularen Kr\u00e4fte \\(\\sim r^{-\\nu_{1,2}}\\) bzw. \\(\\psi,\\,r^{-\\nu_{12}}\\) sind, ist ferner \\(5 (C - 1) = (\\nu_{12} - 5)/(\\nu_{12} - 1)\\), also \\(\\alpha = 0\\) f\u00fcr Maxwellsche Molek\u00fcle (\\(\\nu_{12} = 5\\)). Die Abh\u00e4ngigkeit der \u00fcbrigen Parameter von den \\(\\nu\\) wird in Tabellen angegeben. Einfachere Formeln ergeben sich in Grenzf\u00e4llen: a) \\(M= 1\\); dann ist \\(1/\\alpha\\) linear in \\(c_{1,2}\\); b) Isotope (gleiches Kraftgesetz) mit \\(M\\ll1\\); bei Beschr\u00e4nkung auf lineare Glieder in M ist \\(\\alpha\\) exakt konzentrationsunabh\u00e4ngig und im Fall des Potenzgesetzes gilt ann\u00e4hernd \\(g = (0,89 - 1,5/\\nu + 4/\\nu^2 - 3,15/\\nu^3 )\\cdot M\\); c) Isotope, aber mit be\\-liebigem \\(M\\); das Ergebnis in diesem Fall bei Voraussetzung des Potenzgesetzes wird in Tabellen wiedergegeben; d) Isobare (gleiche Massen) mit wenig verschiedenem Kraftgesetz; hiervon werden wiederum einige Unterf\u00e4lle diskutiert; e) Starre Mo\\-lekeln mit den Durchmessern \\(s_{1,2}\\); in diesem Fall ist \\(\\alpha = 0,89\\, M + 0,34\\, s\\), wo \\(s = (s_1 - s_2)/(s_1 + s_2)\\).","type":"string"},"datatype":"string"},"type":"statement","id":"Q2590132$E5833512-3AE9-44F4-9A7A-B97FD9FA32FA","rank":"normal"}],"P1451":[{"mainsnak":{"snaktype":"value","property":"P1451","hash":"93ab0a2fecb931ce223d6a63e04d4a13c91a94a3","datavalue":{"value":"2509555","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2590132$99512E04-2485-48E8-A7D3-CDCDC9150600","rank":"normal"}],"P1460":[{"mainsnak":{"snaktype":"value","property":"P1460","hash":"57f7fea50d2ce1b39b695c4a1313582eed405e38","datavalue":{"value":{"entity-type":"item","numeric-id":5976449,"id":"Q5976449"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2590132$496CBAEC-69BC-4B27-B6B4-43C209FB018C","rank":"normal"}],"P205":[{"mainsnak":{"snaktype":"value","property":"P205","hash":"10004255e7af7821941ba264d8c3ecf84bb01e9c","datavalue":{"value":"https://doi.org/10.1098/rspa.1940.0110","type":"string"},"datatype":"url"},"type":"statement","id":"Q2590132$D6E0DA1B-43B1-4C8A-92FB-FC2FCC39FF40","rank":"normal"}],"P388":[{"mainsnak":{"snaktype":"value","property":"P388","hash":"c72c49a6ea0fd15ba7d949d0b8dcc50b1fe2357a","datavalue":{"value":"W2098834328","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2590132$1D5E0B67-EE59-492A-AA25-BC04989F422F","rank":"normal"}],"P27":[{"mainsnak":{"snaktype":"value","property":"P27","hash":"124f524949f27539f8aa42b37d0d4f9b373580d7","datavalue":{"value":"10.1098/RSPA.1940.0110","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2590132$DE6B053F-B385-4377-B0E7-F0BC3D7CCE0C","rank":"normal"}],"P200":[{"mainsnak":{"snaktype":"value","property":"P200","hash":"a6c1288eec45915c2822c0387f088f24a50535c9","datavalue":{"value":{"entity-type":"item","numeric-id":3126081,"id":"Q3126081"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2590132$82BAEC19-2077-498B-A4D7-DB28C806132C","rank":"normal"}]},"sitelinks":{"mardi":{"site":"mardi","title":"Publication:2590132","badges":[],"url":"https://portal.mardi4nfdi.de/wiki/Publication:2590132"}}}}}