{"entities":{"Q2623786":{"pageid":2634529,"ns":120,"title":"Item:Q2623786","lastrevid":44508666,"modified":"2025-11-23T10:27:20Z","type":"item","id":"Q2623786","labels":{"en":{"language":"en","value":"On the definition of the Gibbs potential."}},"descriptions":{"en":{"language":"en","value":"scientific article; zbMATH DE number 2545211"}},"aliases":{},"claims":{"P31":[{"mainsnak":{"snaktype":"value","property":"P31","hash":"fd5912e4dab4b881a8eb0eb27e7893fef55176ad","datavalue":{"value":{"entity-type":"item","numeric-id":56887,"id":"Q56887"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2623786$D1908AA3-A923-4240-87B2-6D2ED4DB7197","rank":"normal"}],"P159":[{"mainsnak":{"snaktype":"value","property":"P159","hash":"2e135f52eceb2a20fb904962d556d2e300b73c1f","datavalue":{"value":{"text":"On the definition of the Gibbs potential.","language":"en"},"type":"monolingualtext"},"datatype":"monolingualtext"},"type":"statement","id":"Q2623786$FE9D07CF-2EFC-4B8B-9860-E23FAD0EFA99","rank":"normal"}],"P225":[{"mainsnak":{"snaktype":"value","property":"P225","hash":"e49cbe297cc03f39c4e6d92dd5acb0aa4915d6c0","datavalue":{"value":"59.0780.04","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2623786$8969C605-FE70-40FD-A0DD-E8514536DD94","rank":"normal"}],"P16":[{"mainsnak":{"snaktype":"value","property":"P16","hash":"7b72d590d9efba9db435fa01e5c82bbc4d29b958","datavalue":{"value":{"entity-type":"item","numeric-id":560955,"id":"Q560955"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2623786$9A7ADD1A-3BD7-4269-B46C-B73259BEFDE1","rank":"normal"}],"P28":[{"mainsnak":{"snaktype":"value","property":"P28","hash":"5229eeedf2f969cf3cb5fc8ccac583c702705ed8","datavalue":{"value":{"time":"+1933-00-00T00:00:00Z","timezone":0,"before":0,"after":0,"precision":9,"calendarmodel":"http://www.wikidata.org/entity/Q1985727"},"type":"time"},"datatype":"time"},"type":"statement","id":"Q2623786$C3D2DC52-CF90-4F0B-BFED-A843D8AD2810","rank":"normal"}],"P1448":[{"mainsnak":{"snaktype":"value","property":"P1448","hash":"9904913c61cea02ad6344392459ad00790073bb0","datavalue":{"value":"Man habe ein offenes chemisches System; d. h. es soll erlaubt sein, da\u00df Materie die Grenzen passiert. Nach \\textit{Gibbs} gilt dann f\u00fcr eine reversible \u00c4nderung  \\[  dE = TdS - pdv + \\mu _1dm_1 + \\mu _2dm_2+\\cdots,  \\]  wobei \\(E, S, v, T\\) und \\(p\\) bzw. die Energie, die Entropie, das Volumen, die Temperatur und den Druck bedeuten; \\(dm_1, dm_2, \\ldots \\) bedeuten die Variationen der Masse der einzelnen Komponenten, \\(\\mu _2, \\mu _2,\\ldots \\) die \\textit{Gibbs}schen Potentiale der einzelnen Komponenten, die also definiert sind durch:  \\[  \\mu _1 = \\left (\\frac {dE}{dm_1}\\right )_{S, v, m},\\;\\mu _2 = \\left (\\frac {dE}{dm_2}\\right )_{S,v,m},\\ldots.  \\]  Gegen diese Definition sind von verschiedenen Autoren Einw\u00e4nde erhoben worden, da \\(S, v, m\\) bei einer Zufuhr oder Wegnahme von \\(dm_1, dm_2,\\ldots \\) nicht als konstant anzusehen sind.  Verf. zeigt nun, wie man die \\textit{Gibbs}sche Definition aufrecht erhalten kann, wenn man die Zufuhr von Materie zum System in geeigneter Weise so f\u00fchrt, da\u00df die Entropie keine \u00c4nderung erleidet. Es ergibt sich z. B.  \\[  \\mu _1 = \\varepsilon _1 - Ts_1+p_1v_1,  \\]  wobei \\(\\varepsilon _1, s_1, v_1\\) und \\(p_1\\) die Energie, die Entropie, das Volumen und den Druck der Ma\u00dfeinheit der Komponente bezeichnen, die sich im reinen Zustand im chemischen und thermischen Gleichgewicht mit der Mischung befindet (z. B. durch eine semipermeable Membran).","type":"string"},"datatype":"string"},"type":"statement","id":"Q2623786$8D6D0244-6FDC-49A6-9C23-7327F05E462E","rank":"normal"}],"P1451":[{"mainsnak":{"snaktype":"value","property":"P1451","hash":"48b3bcd0042c80df816a9ccd32f98e6c7f8abe04","datavalue":{"value":"2545211","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q2623786$BFECAFDA-FACB-499D-94A9-093BD21AD61A","rank":"normal"}],"P1460":[{"mainsnak":{"snaktype":"value","property":"P1460","hash":"57f7fea50d2ce1b39b695c4a1313582eed405e38","datavalue":{"value":{"entity-type":"item","numeric-id":5976449,"id":"Q5976449"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q2623786$B4BA0CAE-320E-4D55-9B30-86F3090E7C30","rank":"normal"}]},"sitelinks":{"mardi":{"site":"mardi","title":"Publication:2623786","badges":[],"url":"https://portal.mardi4nfdi.de/wiki/Publication:2623786"}}}}}