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The space \\(PSH(X,\\theta)\\) of \\(\\theta\\)-plurisubharmonic functions consists of all integrable strongly upper semicontinuous functions \\(u\\) on \\(X\\) such that \\(\\theta+dd^cu\\ge 0\\) in the sense of currents. When the class \\([\\theta]\\) in \\(H^{1,1}(X,\\mathbb{R})\\) is pseudo-effective (that is, it contains a positive current), we can define a \\(\\theta\\)-plurisubharmonic function with minimal singularities as the following envelope: \\(u_\\theta(x)=\\sup\\{u(x)\\mid u\\le 0,\\ u\\in PSH(X,\\theta)\\}\\).  The envelope \\(u_\\theta\\) is almost never of class \\(C^2\\); this paper introduces a natural family of smooth regularizations \\(u_\\beta\\) of \\(u_\\theta\\), where \\(\\beta>0\\) is a parameter that can be interpreted as a sort of ``inverse temperature'', and thus the limit \\(\\beta\\to+\\infty\\) can be thought of as a zero temperature limit in the sense of statistical mechanics.  The regularizations \\(u_\\beta\\) are obtained as smooth solutions of a complex Monge-Amp\u00e8re equation of the form \\((\\theta+dd^cu_\\beta)^n=e^{\\beta u_\\beta}\\,dV\\) for a suitable volume form \\(dV\\). The author shows that when \\([\\theta]\\) is a K\u00e4hler class then as \\(\\beta\\to+\\infty\\) the functions \\(u_\\beta\\) converge to \\(u_\\theta\\) in \\(C^{1,\\alpha}(X)\\) for any \\(\\alpha\\in(0,1)\\), with a uniform bound on \\(dd^cu_\\beta\\). The paper contains two proofs of this result. One proof uses a direct simple maximum principle argument. The second one is variational, and extends to the more general case of \\([\\theta]\\) big. In this case, \\(-\\infty\\)-singularities for all \\(\\theta\\)-plurisubharmonic functions can appear; however, when \\([\\theta]\\) is also nef the solutions to the complex Monge-Amp\u00e8re equation above are smooth on the complement \\(\\Omega\\) of a complex subvariety of \\(X\\) depending only on \\([\\theta]\\). The author then shows that when \\([\\theta]\\) is big then the functions \\(u_\\beta\\) converge to \\(u_\\theta\\) uniformly, and moreover when \\([\\theta]\\) is nef the convergence holds in \\(C^{1,\\alpha}_{\\mathrm{loc}}(\\Omega)\\).   The paper then presents applications of these results to the regularization of plurisubharmonic functions and to the theory of weak geodesic rays and test configurations in K\u00e4hler 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