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Let \\(\\mathbf{G}\\) be a finite simple Chevalley or Steinberg group defined over a finite field \\(\\mathbb{F}_{q}\\) where \\(q = p^m\\), with \\(m \\in \\mathbb{N}\\) and \\(p\\) prime. An element of \\(\\mathbf{G}\\) is semisimple, respectively unipotent, if its order is coprime to \\(p\\), respectively a power of \\(p\\). These notions are unambiguous except when \\(\\mathbf{G}\\) is one of the following: \\[ \\mathrm{PSL}_2(4) \\simeq \\mathrm{PSL}_2(5), \\mathrm{PSL}_3(2) \\simeq \\mathrm{PSL}_2(7), \\mathrm{PSU}_4(2) \\simeq \\mathrm{PSp}_4(3). \\] A class is semisimple or unipotent if any element of it is so.  The paper deals with mixed conjugacy classes, i.e., which are neither semisimple nor unipotent. The authors firstly summarize the unipotent conjugacy classes of \\(\\mathbf{G}\\) in the previous four papers of the series. Then they show that  \\begin{itemize} \\item A mixed conjugacy class in a simple Chevalley or Steinberg group collapses. \\item Let \\(q\\) be even and let \\(\\mathbf{G}\\) be a simple group in one of the following families: \\[\\mathrm{PSL}_{2}(q), \\mathrm{PSp}_{2n}(q), \\mathrm{P\\Omega}_{4n}^+(q), \\mathrm{P\\Omega}_{4n}^{-}(q), {^3D}_4(q), E_7(q), E_8(q), F_4(q), G_2(q).\\] Let \\(\\mathcal{H}\\) be a finite-dimensional pointed Hopf algebra whose group of group-like elements is isomorphic to \\(\\mathbf{G}\\). Then \\(\\mathcal{H}\\simeq \\mathbb{C}\\mathbf{G}\\). \\end{itemize}  For Part IV see [the authors, Algebr. Represent. 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