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A Diophantine \\(m\\)-tuple in \\(R\\) is a set of \\(m\\) elements in \\(R\\setminus \\{0\\}\\) such that the product of any two of its distinct elements increased by the unity is a square in \\(R\\). A Diophantine triple \\(\\{a_1, a_2, a_3\\}\\) can be extended to a Diophantine quadruple by adding one of the following two elements (if they are not equal to 0): \\(d_{\\pm} = a_1 + a_2 + a_3 + 2a_1a_2a_3 \\pm 2rst\\), where \\(a_1a_2 +1 = r^2\\), \\(a_1a_3+1 = s^2\\), \\(a_2a_3+1 = t^2\\). Sets of the form \\(\\{a_1, a_2, a_3, d_{-}\\}\\) and \\(\\{a_1, a_2, a_3, d_{+}\\}\\) (if \\(d_{\\pm} \\neq 0\\)) are called regular Diophantine quadruples. If \\(d_{-}d_{+} + 1 = \\square\\) and \\(d_{\\pm} \\neq 0\\), then \\(\\{a_1, a_2, a_3, d_{+}, d_{-}\\}\\) represents a Diophantine quintuple and such a set will be called a biregular Diophantine quintuple.\\par In this paper, the biregular Diophantine quintuples in the ring \\(\\mathbb{Z}[\\sqrt{D}]\\), where \\(D\\) is a positive integer which is not a perfect square, are studied. Suppose that \\(D = 1 + n^2(n + 1)^2\\), where \\(n\\) is a positive integer. Then, it is proved that there exists a biregular Diophantine quintuple in \\(\\mathbb{Z}[\\sqrt{D}]\\) of the form \\(\\{e, a + b\\sqrt{D}, a -b\\sqrt{D}, c + d\\sqrt{D}, c-d\\sqrt{D}\\}\\), such that \\(a, b, c, d, e \\in \\mathbb{Z}\\) and \\(c \\pm d \\sqrt{D}\\) correspond to the regular extensions \\(d_{\\pm}\\) generated by the triple \\(\\{e, a + b\\sqrt{D}, a - 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