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notion of the canonical module of a module, which was defined by \\textit{P. Schenzel} [Dualisierende Komplexe in der lokalen Algebra und Buchsbaum-Ringe. Lecture Notes in Mathematics. 907. Berlin-Heidelberg-New York: Springer-Verlag. (1982; Zbl 0484.13016)], is an important tool in commutative algebra. In the paper under review, the authors generalize this concept to complexes. Let \\((R, \\mathfrak m)\\) be a commutative Noetherian local ring admitting a dualizing complex. Let \\(D_R\\) denotes the dualizing complex normalized with \\(\\sup D_R=\\dim R\\) and \\(\\inf D_R=\\mathrm{depth }R\\). Let \\(D(R)\\) be the category of complexes of \\(R\\)-modules and \\(M\\in D_b^f(R)\\) where the subscripts ``b'' and ``f'' denote the homological boundness and the homological finiteness, respectively. For every \\(i\\in \\mathbb Z\\), set \\(K^i_M = H_i(M^{\\dagger})\\) where \\(M^{\\dagger}=\\mathbf{R}\\mathrm{Hom}_R(M, D_R)\\). The module \\(K^{\\dim R}_M\\), denoted by \\(K_M\\), is called the canonical module of \\(M\\). Let \\(k\\in \\mathbb Z\\) and \\(N\\in D_b^f(R)\\). A complex \\(M\\in D_b^f(R)\\) is said to satisfy the Serre's condition \\((S_{k,N})\\) if NEWLINE\\[NEWLINE\\mathrm{depth}_{R_{\\mathfrak p}} \\mathbf{R}\\mathrm{Hom}_{R_{\\mathfrak p}} (N_{\\mathfrak p}, M_{\\mathfrak p}) \\geq \\min\\{ k, \\dim_{R_{\\mathfrak p}} M_{\\mathfrak p} + \\inf N_{\\mathfrak p}\\}\\text{ for all }\\mathfrak p\\in \\mathrm{Spec }R.NEWLINE\\]NEWLINE One of the main results of the paper says that if \\(t=\\dim_R M\\) and \\(M\\) is equidimensional, then the following conditions are equivalent: (i) \\(M\\) satisfies condition \\((S_{k,N})\\); (ii) The natural homomorphism \\(\\mathrm{Ext}^{-i}_R(N, M)\\longrightarrow K^{i+t}_{N\\otimes^{L}_{R}{K_M}}\\) is bijective for all \\(i\\geq{-k+2}\\), and injective for 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