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The authors define and study relative derived category of \\(\\mathcal S\\) with respect to \\(\\mathcal X\\), \\({\\mathbf D}^*_{\\mathcal X}(\\mathcal S)\\) (*\\(\\in \\{\\mathrm{blank}, -, b\\}\\)), as the Verdier quotient of the homotopy category \\({\\mathbf K}^*(\\mathcal S)\\) with respect to thick triangulated subcategory of all \\(\\mathcal X\\)-acyclic complexes in \\({\\mathbf K}({\\mathcal S})\\). It is shown that when \\(\\mathcal X\\) is exact and has an injective cogenerator, there exists a triangle equivalence between \\({\\mathbf K}^-(\\mathcal X)\\) and \\({\\mathbf D}^-_{\\mathcal X}(\\mathrm{res }\\hat {\\mathcal X})\\), where \\(\\mathrm{res }\\hat{\\mathcal X}\\) is the subcategory of objects in \\(\\mathcal A\\) with finite \\(\\mathcal X\\)-projective dimension. This results extends the bounded case of Gorenstein projective modules showed by \\textit{N. Gao} and \\textit{P. Zhang} [J. Algebra 323, No. 7, 2041--2057 (2010; Zbl 1222.18005)]. 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