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Though many performance measures have been proposed, few measures were specially defined for multi-class problems, which tend to be more complicated than two-class problems, especially in addressing the issue of class discrimination power. Confusion entropy was proposed for evaluating classifiers in the multi-class case. Nevertheless, it makes no use of the probabilities of samples classified into different classes. In this paper, we propose to calculate confusion entropy based on a probabilistic confusion matrix. Besides inheriting the merit of measuring if a classifier can classify with high accuracy and class discrimination power, probabilistic confusion entropy also tends to measure if samples are classified into true classes and separated from others with high probabilities. 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