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A non-zero submodule \\(S\\) of \\(M\\) is called second, if for each \\(r\\in R\\), either \\(rS=0\\) or \\(rS=S\\). Suppose that \\(\\mathrm{X}^s(M)\\) is the set of all second submodules of \\(M\\) and \\(\\mathrm{W}^s(N)=\\{S\\in \\mathrm{X}^s(M)| S\\nsubseteq N\\}\\) for each submodule \\(N\\) of \\(M\\). Then the authors define the second classical Zariski topology of \\(M\\) as the topology on \\(\\mathrm{X}^s(M)\\) generated by the sub-basis \\(A=\\{\\mathrm{W}^s(N)|N\\leq M\\}\\), which means that open sets of this topology are unions of finite intersections of elements in \\(A\\).  The authors first study some general properties of this topology and \\(\\mathrm{X}^s(M)\\) such as being Hausdorff or T\\(_1\\). Then they turn their attention to the question ``when the second classical Zariski topology of \\(M\\) is spectral?'', where by a spectral space we mean a topological space homeomorphic to the prime spectrum of a commutative ring equipped with the Zariski topology. 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