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A PRO is a combinatorial object defined on a bigraded set \\((\\mathcal P)=\\sqcup {\\mathcal P}(p,q)\\), where \\(p\\) and \\(q\\) represent the input and output arity of the objects (as if they were functions). The PRO has operations \\(*: {\\mathcal P}(p,q)\\times {\\mathcal P}(p^\\prime,q^\\prime)\\to {\\mathcal P}(p+p^\\prime,q+q^\\prime)\\) and \\(\\circ: {\\mathcal P}(q,r)\\circ{\\mathcal P}(p,q)\\to {\\mathcal P}(p,r)\\) analogous to concatenation and composition. A stiff PRO is a free PRO modulo a congruence relation which preserves a natural combinatorial decomposition property.  The authors give a natural construction of a combinatorial Hopf algebra from a stiff PRO. The construction generalizes the classical construction from an operad of \\textit{P. van der Laan} [Operads. Hopf algebras and coloured Koszul duality. Utrecht: Universiteit Utrecht (PhD Thesis) (2004)]. This gives a construction of the deformed Fa\u00e0 di Bruno algebra of \\textit{L. Foissy} [Adv. 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Other natural examples include several tree-like structures; for example, a PRO and thus a combinatorial Hopf algebra can be constructed on heaps of pieces (objects of a fixed integer width which may be stacked at integer points) and friable pieces (analogous objects which break into 1-wide pieces and fall under 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