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In the graphs, each vertex represents an atom of molecule and edges between the corresponding vertices are used to represent covalent bounds between atoms. The \\textit{Wiener polarity index} \\(W_p(G)\\) of a graph \\(G\\) is the number of unordered pairs of vertices \\(u, v\\) of \\(G\\) such that the distance between \\(u\\) and \\(v\\) is equal to 3. The trees and unicyclic graphs with perfect matching, of which all vertices have degrees not greater than three, are referred to as the \\textit{H\u00fcckel trees} and \\textit{unicyclic H\u00fcckel graphs}, respectively. In this paper, we first consider the smallest and the largest Wiener polarity index among all H\u00fcckel trees on \\(2 n\\) vertices and characterize the corresponding extremal graphs. 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