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An operator \\(A'\\) is said to be a {\\textit{proper}} extension of the dual pair \\((A,\\widetilde{A})\\) if \\(A\\subset {A'}\\subset\\widetilde{A}^*\\), resp., \\(\\widetilde{A}\\subset ({A'})^*\\subset A^*\\). It is assumed that \\(\\mathcal D(A)\\cap\\mathcal D(\\widetilde A)\\) is dense in \\(\\mathcal H\\). Denote by \\(V:=\\frac{A-\\widetilde{A}}{2i}\\) the non-negative symmetric operator with domain \\(\\mathcal D(V) = \\mathcal D(A)\\cap\\mathcal D(\\widetilde A)\\) or \\(\\mathcal D(V)=\\mathcal D\\) if \\(A\\) and \\(\\widetilde A\\) have common core \\(\\mathcal D\\). Let \\(V_K\\) be the Krein-von Neumann extension of \\(V\\) and \\(V_F\\) be the Friedrichs extension of \\(V\\).  The authors present a method of determining the proper dissipative extensions \\(\\widehat A\\) of this dual pair. Let \\(\\mathcal{V}\\subset\\mathcal{D}(\\widetilde{A}^*)/\\mathcal{D}(A)\\) be a linear space. Define the operator \\(A_\\mathcal{V}=\\widetilde{A}^*\\upharpoonright_{\\mathcal{D}(A_\\mathcal{V})}\\) with \\(\\mathcal{D}(A_\\mathcal{V})=\\mathcal{D}(A)\\dot{+}\\mathcal{V} \\). It is proved that the operator \\(A_\\mathcal{V}\\) is dissipative if and only if \\(\\mathcal{V}\\subset\\mathcal{D}(V_K^{1/2})\\) and \\(\\operatorname{Im}\\langle v,\\widetilde{A}^*v\\rangle\\geq \\|V_K^{1/2}v\\|^2\\) for all \\(v\\in\\mathcal{V}\\).  Let \\(\\mathcal{N}_C\\) denotes the numerical range of an operator \\(C\\). The authors prove that \\(\\inf\\limits_{z\\in\\mathcal{N}_{A}}\\operatorname{Im} z= \\inf\\limits_{z\\in\\mathcal{N}_{A_\\mathcal{V}}}\\operatorname{Im} z\\) for any extension \\(A_{\\mathcal{V}}\\) with \\(\\mathcal{V}\\subset\\mathcal{D}(V_F^{1/2})\\).  Applications to symmetric operators, symmetric operators perturbed by a relatively bounded dissipative operator, and more singular differential operators are 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