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paper is devoted to the asymptotic analysis of the parameter \\(\\varepsilon\\) of a kinetic system situated at a small Knudsen number regime with given in date boundary conditions NEWLINE\\[NEWLINE\\begin{aligned} \\xi \\frac{\\partial}{\\partial x}f^{A}(x,v)&=\\frac{1}{\\varepsilon}Q(f^{A},f^{A})(x,v) +Q(f^{A},f^{B})(x,v), \\\\ \\xi \\frac{\\partial}{\\partial x}f^{B}(x,v)&=\\frac{1}{\\varepsilon}Q(f^{B},f^{A})(x,v) +Q(f^{B},f^{B})(x,v), \\\\ x&\\in [-1,+1],\\quad v\\in \\mathbb{R}^3\\end{aligned}NEWLINE\\]NEWLINE with \\(\\varepsilon=\\frac{\\sqrt{\\pi}}{2}K_n=\\frac{\\sqrt{\\pi}l}{4}\\), \\(l=\\frac{1}{\\sqrt{2}\\pi d^2n_{I}}\\). \\(l\\) is the mean free path of the vapor molecules in the equilibrium state at rest with temperature \\(T_{I}\\) and density \\(n_{I}\\), \\(K_{n}\\) is the Knudsen number and \\(d\\) corresponds to the diameter of the molecule. \\(Q\\) is a collision operator and is defined by NEWLINE\\[NEWLINE 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NEWLINE\\]NEWLINE The velocity \\(v\\in \\mathbb{R}^3\\) has the coordinates \\((\\xi,\\eta,\\chi)\\), \\(\\langle,\\rangle\\) denotes the Euclidean scalar product in \\(\\mathbb{R}^3\\), and \\(\\omega\\in S^2\\) represented by the polar angle (with axis along \\(v-v_{*}\\)) and the azimuthal angle \\(\\phi.\\) The function \\(B(v-v_{*},\\omega)=|\\langle v-v_{*},\\omega\\rangle|\\) is the collision kernel of the collision operator \\(Q\\) considered in the situation of the hard-sphere. The boundary condition for the \\(A\\) and \\(B\\) components satisfy the following in data profile NEWLINE\\[NEWLINE \\begin{aligned} f^{A}(-1,v)&=\\frac{p^{A}_{I}/T_{I}}{(\\pi T_{I})^{\\frac{3}{2}}}\\exp(-\\frac{v^2}{T_{I}}), \\quad \\xi>0,\\\\ f^{A}(1,v)&=\\frac{p^{A}_{II}/T_{II}}{(\\pi T_{II})^{\\frac{3}{2}}}\\exp(-\\frac{v^2}{T_{II}}), \\quad \\xi<0, \\\\ f^{B}(-1,v)&=\\frac{p^{B}_{I}/T_{I}}{(\\pi T_{I})^{\\frac{3}{2}}}\\exp(-\\frac{v^2}{T_{I}}), \\quad \\xi>0, \\\\ f^{B}(1,v)&=\\frac{p^{B}_{II}/T_{II}}{(\\pi T_{II})^{\\frac{3}{2}}}\\exp(-\\frac{v^2}{T_{II}}), \\quad \\xi<0. \\end{aligned} NEWLINE\\]NEWLINE \\(T_{I}\\) (resp., \\(T_{II}\\)) represents the temperature of the condensed phase situated at \\(x=-1\\) (resp., \\(x=1\\)) and \\(p^{\\alpha}_I\\) is the saturation pressure of species \\(\\alpha\\) at temperature \\(T_{I}\\) (resp., \\(T_{II}\\)). \\(T_{I}=p^{A}_{I}=1\\). 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