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There are mainly two such pairings in the literature, namely:  -- The Shklyarov pairing, introduced in the DG-framework in the preprint [\\textit{D. Shklyarov}, ``Hirzebruch-Riemann-Roch theorems for DG-algebras'', \\url{arXiv:0710.1937}].  -- The Mukai pairing, defined by \\textit{A. C\u0103ld\u0103raru} and \\textit{S. Willerton} in [New York J. Math. 16, 61--98 (2010; Zbl 1214.14013)] via Serre duality.  Results of \\textit{N. Markarian} [J. Lond. Math. Soc., II. Ser. 79, No. 1, 129--143 (2009; Zbl 1167.14005)] and the author [New York J. Math. 14, 643--717 (2008; Zbl 1158.19002)] imply that the Mukai pairing on a variety \\(X\\) is given (up to sign) via the Hochschild-Kostant-Rosenberg isomorphism by the formula \\(<a, b>=\\int_X a \\wedge b \\wedge \\mathrm{Td} (X)\\). Later on, it has been proved by the author [Mosc. Math. J. 10, No. 3, 629--645 (2010; Zbl 1208.14013)] that the two aforementioned pairings were the same up to signs.  The aim of the current paper is to obtain directly the expression of the Shklyarov pairing. The method relies on the theory of deformation quantization as developed in [\\textit{M. Kashiwara} and \\textit{P. Schapira}, Deformation quantization modules. Ast\u00e9risque 345. Paris: Soci\u00e9t\u00e9 Math\u00e9matique de France (2012; Zbl 1260.32001)] as well as on the index theorem of \\textit{P. Bressler, R. Nest} and \\textit{B. Tsygan} [Adv. Math. 167, No. 1, 1--25 (2002; Zbl 1021.53064); ibid. 167, No. 1, 26--73 (2002; Zbl 1021.53065)]. Using this, the proof reduces to prove that the Euler class of the structural sheaf \\(\\mathcal{O}_X\\) is the Todd class of \\(X\\). This fact has been conjectured by Kashiwara in 1991 and proved by the reviewer in [J. Differ. Geom. 90, No. 2, 267--275 (2012; Zbl 1247.32013)]. 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