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It starts with investigations on discrete Schr\u00f6dinger operators on graphs, Wronskians and topology by introducing finite-type operators, finite-order operators, orders of operators and second-order operators. It follows an attempt to find and to use a natural analogue of the Wronskian for any pair of operators for any finite-order Schr\u00f6dinger operator on arbitrary graphs satisfying suitable conditions. Next, the author introduces asymptotic symplectic spaces, asymptotic vectors, spaces of symplectic data and scattering zone of normal discrete spectrum and asserts that the scattering zone of the scattering matrix is always unitary and symmetric. Further, the studies of the factorization of the Schr\u00f6dinger operator on graphs leads to the equivalence of a set of equations to the representation of operators in factorized form. 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