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We derive a formula (an extension of a formula due to Pushnitski) relating the spectral shift function \\(\\xi(\\cdot ;A_+,A_-)\\) for the pair \\((A_+,A_-)\\), and the corresponding spectral shift function \\(\\xi(\\cdot ;\\mathbf {H_2,H_1})\\) for the pair of operators \\((\\mathbf {H_2,H_1})=(\\mathbf{D_AD^*_A,D^*_AD_A})\\) in this relative trace class context. This formula is then used to identify the Fredholm index of \\(\\mathbf{D_A}\\) with \\(\\xi(0;A_+,A_-)\\). In addition, we prove that index(\\(\\mathbf{D_A}\\)) coincides with the spectral flow SpFlow\\((\\{A(t)\\}^{\\infty}_{t=-\\infty})\\) of the family \\(\\{A(t)\\}_{t\\in\\mathbb R}\\) and also relate it to the (Fredholm) perturbation determinant for the pair \\((A_+,A_-)\\). We also provide some applications in the context of supersymmetric quantum mechanics to zeta function and heat kernel regularized spectral asymmetries and the 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