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In this paper, the structure of the Witt ring \\(W{\\mathcal O}_S(K)\\) is determined. This Witt ring is finitely generated as an abelian group; its decomposition into cyclic summands is determined by explicitly describing generators of these summands given by \\(1\\)-dimensional, binary, or \\(2\\)-fold Pfister forms. In the case of a global number field and for \\(S\\) the set of infinite primes (i.e. \\({\\mathcal O}_S(K)\\) is the ring of algebraic integers), this has already been done by the author in [Pr. Nauk. Uniw. Slask. Katowicach 1751, Ann. Math. Silesianae 12, 105-121 (1998; Zbl 0924.11026)], and the methods used there have been generalized in the present paper. The author also studies under which conditions there exist Witt ring isomorphisms \\(W{\\mathcal O}_S(K)\\cong W{\\mathcal O}_{S'}(L)\\), and necessary and sufficient conditions for the existence of Witt ring isomorphisms \\(WK\\to WL\\) mapping the Witt ring \\(W{\\mathcal O}_{S}(K)\\) onto \\(W{\\mathcal O}_{S'}(L)\\). 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