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Beals, D. H. Sattinger} and \\textit{J. Szmigielski}, [Adv.\\ Math.\\ 154, No.\\ 2, 229--257 (2000; Zbl 0968.35008)] and \\textit{H. P. McKean}, [Commun.\\ Pure Appl.\\ Math.\\ 56, No.\\ 7, 998--1015 (2003; Zbl 1037.37030)] it is known that a Liouville transform allows one to pass from an equation of the Korteweg-de Vries (K-dV) hierarchy  \\[  u_t=3uu_x-\\frac{1}{2}u_{xxx}  \\]  to a corresponding equation of the Camassa-Holm (CH) hierarchy  \\[  4u_t=u_{xxt}+1uu_{xxx}+4u_xu_{xx}-24uu_x.  \\]  This paper presents a systematic development of the correspondence between these two hierarchies using coefficients of the asymptotic expansion of certain Green's functions. In doing so, the authors obtain a new class of solutions to the CH hierarchy. 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