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Under regularity assumptions on the coefficients of heat conductivity, the kinetic undercooling and the free energy, the main result of the paper states that the moving interface is jointly \\(C^k\\)-smooth in time and space, for \\(k\\in\\mathbb{N}\\cup\\{\\infty, \\omega\\}\\), where \\(\\omega\\) is the symbol for real analyticity. The authors approach this problem by using a family of parameter-dependent diffeomorphisms, \\(L_p\\)-maximal regularity theory, and the implicit function theory.NEWLINENEWLINEIn more detail, the authors consider a general model for phase transitions that is thermodynamically consistent. It is assumed that there is no entropy production on the interface.NEWLINENEWLINEWe let \\(\\Omega\\subset \\mathbb{R}^{m+1}\\) be a bounded domain of class \\(C^2\\), for \\(m\\geq 1\\), and we assume that \\(\\Omega\\) is occupied by a material that can undergo phase changes in such a way that at time \\(t\\), the phase \\(i\\) occupies the subdomain \\(\\Omega_i\\) of \\(\\Omega\\) for \\(i=1,2\\). It is assumed that no boundary contact can occur, i.e., \\(\\partial\\Omega_i\\cap \\partial\\Omega=\\emptyset\\). The interface between the phases is the hypersurface \\(\\Gamma(t):=\\partial\\Omega_1(t)\\subset\\Omega\\). The Stefan problem with surface tension, possibly with kinetic undercooling, studied in this paper can be formulated then as finding a family of closed compact hypersurfaces \\(\\{\\Gamma(t)\\}_{t\\geq 0}\\) contained in \\(\\Omega\\) and an appropriately smooth function \\(\\theta: \\mathbb{R}_+\\times\\overline{\\Omega}\\rightarrow \\mathbb{R}\\) such that NEWLINENEWLINENEWLINENEWLINE\\[NEWLINE\\begin{aligned} \\kappa(\\theta)\\partial_t\\theta -\\text{div}(d(\\theta)\\nabla \\theta) & =0 \\;\\text{ in } \\Omega\\setminus\\Gamma(t), \\\\ NEWLINE\\partial_{\\nu_{\\Omega}}\\theta & =0 \\;\\text{ on } \\partial\\Omega, \\\\NEWLINE[[\\theta]] & =0 \\;\\text{ on } \\Gamma(t), \\\\ NEWLINE[[\\psi(\\theta)]]+\\sigma\\mathcal{H} & =\\gamma(\\theta)V \\;\\text{ on } \\Gamma(t),\\\\NEWLINE[[d(\\theta)\\partial_{\\nu_{\\Gamma}}\\theta]] & = ( l(\\theta)-\\gamma(\\theta))V)V \\;\\text{ on } \\Gamma(t),\\\\NEWLINE\\theta(0) & =\\theta_0, \\;\\Gamma(0) =\\Gamma_0. \\end{aligned}NEWLINE\\]NEWLINE NEWLINEHere, \\(\\theta\\) denotes the (absolute) temperature, \\(\\psi_i(\\theta)\\) are the free energies, \\(\\nu_{\\Gamma}(t)\\) is the outer normal field of \\(\\partial\\Omega_1(t)\\), \\(V(t)\\) is the normal velocity of \\(\\Gamma(t)\\), \\(\\mathcal{H}(t)=\\mathcal{H}(\\Gamma(t))=-\\text{div}_{\\Gamma(t)}\\nu_{\\Gamma}(t)/m\\) is the mean curvature of \\(\\Gamma(t)\\) and \\([[v]]\\) is the jump of a quantity \\(v\\) across \\(\\Gamma(t)\\). Moreover, \\(\\kappa_i(\\theta)=-\\theta\\psi_i''(\\theta)\\) indicates the heat capacity and \\(l(\\theta)=\\theta[[\\psi'(\\theta)]]\\) indicates the latent heat. Finally, \\(d_i(\\theta)>0\\) denotes the coefficient of heat conduction in Fourier's law and \\(\\gamma(\\theta)\\geq 0\\) is the coefficient of kinetic undercooling.NEWLINENEWLINEThe main results of the paper state that, if \\(d_i,\\gamma \\in C^{k+2}(0,\\infty)\\), \\(\\psi_i\\in C^{k+3}(0,\\infty)\\), then under certain regularity, compatibility and well-posedness conditions (which depend on whether \\(\\gamma \\equiv 0\\) or not), there exists a unique \\(L_p\\)-solution \\((u,\\Gamma)\\) for the Stefan problem with surface tension on some possibly small but non-trivial time interval \\(J=[0,T]\\) and NEWLINENEWLINE\\[NEWLINE \\mathcal{M}:=\\cup_{t\\in (0,T)}\\{ \\{t\\}\\times \\Gamma(t)\\} NEWLINE\\]NEWLINE NEWLINEis a \\(C^k\\)-manifold in \\(\\mathbb{R}^{m+2}\\). 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