{"entities":{"Q5971963":{"pageid":8148759,"ns":120,"title":"Item:Q5971963","lastrevid":97795400,"modified":"2026-06-05T15:25:51Z","type":"item","id":"Q5971963","labels":{"en":{"language":"en","value":"Das Prinzip von Le Chatelier und Braun."}},"descriptions":{"en":{"language":"en","value":"scientific article; zbMATH DE number 2539234"}},"aliases":{},"claims":{"P31":[{"mainsnak":{"snaktype":"value","property":"P31","hash":"fd5912e4dab4b881a8eb0eb27e7893fef55176ad","datavalue":{"value":{"entity-type":"item","numeric-id":56887,"id":"Q56887"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q5971963$8AFE0EC9-44A2-44A5-A889-804A9B472F10","rank":"normal"}],"P159":[{"mainsnak":{"snaktype":"value","property":"P159","hash":"0d5cf7bf5c8bcfc69561741de1cca4051c09dfc6","datavalue":{"value":{"text":"Das Prinzip von Le Chatelier und Braun.","language":"en"},"type":"monolingualtext"},"datatype":"monolingualtext"},"type":"statement","id":"Q5971963$CB5AF90A-37A0-438C-8541-C91BF095E982","rank":"normal"}],"P225":[{"mainsnak":{"snaktype":"value","property":"P225","hash":"ca55a168cd5e7aeaa590e1b05081ecb3c9774fed","datavalue":{"value":"60.0741.04","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q5971963$B4A2F236-561D-4D38-B640-BCF8D6B74A4D","rank":"normal"}],"P16":[{"mainsnak":{"snaktype":"value","property":"P16","hash":"fb8f3f1b238b82b0e61011d9c066d070470ca174","datavalue":{"value":{"entity-type":"item","numeric-id":1832296,"id":"Q1832296"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q5971963$12360F51-45ED-4265-BF1C-C28CB0F366E3","rank":"normal"}],"P200":[{"mainsnak":{"snaktype":"value","property":"P200","hash":"24995537f64b571df368faeaf2dead30e12c6329","datavalue":{"value":{"entity-type":"item","numeric-id":560247,"id":"Q560247"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q5971963$CD6FC462-694A-4F7A-9B3D-1F077F3EB29D","rank":"normal"}],"P28":[{"mainsnak":{"snaktype":"value","property":"P28","hash":"0545e869d8296a0b0654ccbe2e3181b7f2652da8","datavalue":{"value":{"time":"+1934-00-00T00:00:00Z","timezone":0,"before":0,"after":0,"precision":9,"calendarmodel":"http://www.wikidata.org/entity/Q1985727"},"type":"time"},"datatype":"time"},"type":"statement","id":"Q5971963$AE9577B0-161A-4111-BA81-947736A43DD4","rank":"normal"}],"P1448":[{"mainsnak":{"snaktype":"value","property":"P1448","hash":"649daf2f25c38ee2d75063f7b7151cabbff9874c","datavalue":{"value":"Es wird dem Prinzip eine mathematische Formulierung gegeben. Sind \\(x_1\\) und \\(x_2\\) zwei Parameter und \\(y_1\\) und \\(y_2\\) die zugeh\u00f6rigen Kr\u00e4fte in dem Sinne, da\u00df \\(y_i \\delta x_i\\) die \u00e4u\u00dfere Arbeit darstellt, so l\u00e4\u00dft sich dem Prinzip die Formulierung geben:  \\[  \\left ( \\frac {\\partial y_1}{\\partial x_1} \\right )_{x_2} \\cdot \\left ( \\frac {\\partial y_1}{\\partial x_2} \\right )_{x_1} \\cdot \\left ( \\frac {\\partial y_2}{\\partial x_1} \\right )_{x_2} \\cdot \\left ( \\frac {\\partial y_2}{\\partial x_2} \\right )_{x_2} < 0,  \\]  die f\u00fcr den Fall, da\u00df die Kr\u00e4fte aus einem Potential ableitbar sind, sich zu  \\[  \\left ( \\frac {\\partial y_1}{\\partial x_1} \\right )_{x_2} \\cdot \\left ( \\frac {\\partial y_2}{\\partial x_2} \\right )_{x_1} < 0  \\]  vereinfachen l\u00e4\u00dft. Ist das Potential insbesonderen gleich der Energie, so ist  \\[  \\delta E=y_1 \\delta x_1 + y_2 \\delta x_2.  \\]  Nun m\u00fcssen, da die Energie im stabilen Gleichgewicht ein Minimum hat, beide Differentialquotienten positiv sein, was dem Prinzip widerspricht. Es kann also in dieser Allgemeinheit nicht richtig sein. Wenn man zwischen Quantit\u00e4tsgr\u00f6\u00dfen als jenen, deren Kr\u00e4ftefunktion mit der Energie des Gebildes zusammenf\u00e4llt, und Intensit\u00e4tsgr\u00f6\u00dfen als den dazugeh\u00f6rigen Kr\u00e4ften unterscheidet, so l\u00e4\u00dft sich das Prinzip eindeutig formulieren. Dabei ergibt sich, da\u00df die Natur nicht immer f\u00fcr die Aufrechterhaltung eines Gleichgewichtszustandes sorgt. Das richtig formulierte Prinzip sagt n\u00e4mlich aus, da\u00df der zweite, sich selbst \u00fcberlassene Parameter die Verschiebung des ersten vergr\u00f6\u00dfert oder verkleinert, je nachdem, ob beide Parameter derselben oder verschiedenen Arten von Zustandsgr\u00f6\u00dfen angeh\u00f6ren.","type":"string"},"datatype":"string"},"type":"statement","id":"Q5971963$C9196A33-31BD-4005-A193-3151572E507B","rank":"normal"}],"P1451":[{"mainsnak":{"snaktype":"value","property":"P1451","hash":"0792eaf40ca50bfbbf71068b2095fed86e318c8d","datavalue":{"value":"2539234","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q5971963$883DE046-F546-43DB-815B-85C72A745261","rank":"normal"}],"P1460":[{"mainsnak":{"snaktype":"value","property":"P1460","hash":"57f7fea50d2ce1b39b695c4a1313582eed405e38","datavalue":{"value":{"entity-type":"item","numeric-id":5976449,"id":"Q5976449"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q5971963$3EAEDFDE-E8E5-430F-B3AF-5ED1C6DF59D8","rank":"normal"}],"P205":[{"mainsnak":{"snaktype":"value","property":"P205","hash":"f46e6288df34366790cd56d25062603ff9097dd5","datavalue":{"value":"https://doi.org/10.1002/andp.19344110706","type":"string"},"datatype":"url"},"type":"statement","id":"Q5971963$A5773A29-A06F-415E-8C3E-4CD0FE0E7FF4","rank":"normal"}],"P388":[{"mainsnak":{"snaktype":"value","property":"P388","hash":"884d11dbaa9f3e411632bd9794fecc4ef781bb18","datavalue":{"value":"W2034544161","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q5971963$95B4A21A-10E3-4569-8D4E-C2090B5B4917","rank":"normal"}],"P27":[{"mainsnak":{"snaktype":"value","property":"P27","hash":"ccf111b97d58caaeea7d77a2db436fb28aecae90","datavalue":{"value":"10.1002/ANDP.19344110706","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q5971963$6C30565E-C608-4B32-A928-FB23D76759AB","rank":"normal"}]},"sitelinks":{"mardi":{"site":"mardi","title":"Das Prinzip von Le Chatelier und Braun.","badges":[],"url":"https://portal.mardi4nfdi.de/wiki/Das_Prinzip_von_Le_Chatelier_und_Braun."}}}}}