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It was introduced in the seventies by \\textit{G. Gallavotti} and \\textit{E. Verboven} [``On the classical KMS boundary condition'', Il Nuovo Cimento B 28, No. 1, 274--286 (1975; \\url{doi:10.1007/bf02722820})] as an alternative to the Dobrushin-Lanford-Ruelle (DLR) equation. In this article, we consider this concept in the framework of nonlinear Hamiltonian PDEs and discuss its relevance. In particular, we prove that Gibbs measures are the unique KMS equilibrium states for such systems. Our proof is based on Malliavin calculus and Gross-Sobolev spaces. The main feature of our work is the applicability of our results to the general context of white noise, abstract Wiener spaces and Gaussian probability spaces, as well as to fundamental examples of PDEs like the nonlinear Schr\u00f6dinger, Hartree, and wave (Klein-Gordon) 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