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The main application is the Laplace operator on a infinite weighted graph.  A duality pair \\((\\Delta, \\mathcal C)\\) consists of a densely defined hermitian operator \\(\\Delta\\) on a Hilbert space \\(H\\) and a closed subspace \\(\\mathcal C\\) with \\(\\mathcal C \\subseteq \\ker(\\Delta^*)\\). In this case, \\(\\Delta\\) admits a hermitian extension \\(\\Delta_{\\mathcal C}\\) to \\(\\mathcal D(\\Delta)+\\mathcal C\\) and the domain of its adjoint is \\(\\mathcal D(\\Delta_{\\mathcal C}^*) = H \\ominus \\mathcal C\\).  The author investigates the reproducing kernel Hilbert space with base point \\(o\\), \\((H,X,o)\\), under the additional assumptions that all Dirac functions \\(\\delta_x\\), \\(x\\in X\\), belong to \\(H\\) and that \\(H = \\overline{\\text{span}}\\{k(\\cdot, x) | x\\in X, x\\neq o\\}\\) (\\(k\\) is the kernel function of \\(H\\)). He shows that, under this condition, the operator \\(\\Delta|_V\\) defined by \\((\\Delta|_V f)(x) = \\langle \\delta_x,\\, f\\rangle\\) with domain \\(\\text{span}\\{ k_x - k_o| x\\in X, x\\neq o\\}\\) is densely defined and positive. Moreover, \\((\\Delta|_V, \\mathcal C)\\) is a duality pair, where \\(\\mathcal C = \\{ u \\in H : \\langle y,\\, \\delta_x \\rangle = 0,\\;x \\in X\\}\\), so \\(\\Delta|_V\\) can be extended to a hermitian operator \\(\\Delta_H\\) on \\(\\mathcal D(\\Delta|_V) + \\mathcal C\\). It is shown that \\(\\Delta_H\\) is essentially selfadjoint if and only if \\(\\Delta|_F\\) with domain \\(\\mathcal D(\\Delta|_F) = \\text{span}\\{ \\delta_x | x\\in X\\}\\) is essentially selfadjoint. The paper concludes with an application to an infinite weighted 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