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In the present work, the author computed the Brauer group of the nonconnective spectral Deligne-Mumford stack \\((\\mathscr M, \\mathscr O)\\), where \\(\\mathscr O\\) is Goerss, Hopkins, and Miller's sheaf of \\(\\mathbb E_\\infty\\)-ring spectra with \\(\\mathrm{TMF}\\) the spectrum of its global sections. In both cases away from the prime 2 and at 2, they found that the Brauer group is nontrivial. The nontriviality manifests the presence of derived, nonclassical Azumaya algebras. As such, this continues the line of research by the first named author, Gepner, Lawson, and others on the Brauer groups of commutative ring spectra \\(R\\), among other arithmetic invariants. 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