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The paper explores the role of minimal surfaces of index one in general relativity.\\N\\NLet \\((M,g)\\) be a Riemannian \\(3\\)-manifold, \\(E\\) a tangent vector field and \\(V\\) a positive smooth function on \\(M\\). We say \\((M, g, V, E)\\) is an electrostatic system if \\((M, g)\\) is oriented and the following equations are satisfied\\N\\begin{align*}\\N\\mathrm{Hess}_{g}V &=V(\\mathrm{Ric}_{g}-\\Lambda g +2E^{b}\\otimes E^{b} - |E|^{2}g), \\\\\\N\\Delta_{g}V&=(|E|^{2}-\\Lambda)V, \\\\\\N\\mathrm{div}_{g}E&=0, \\\\\\N\\mathrm{curl}_{g}(VE)&=0, \\\\\\N\\end{align*}\\Nfor some constant \\(\\Lambda \\in \\mathbb{R}\\). Moreover, the system is called complete, if \\((M, g)\\) is complete.\\N\\NThe authors prove the following results that link index-one minimal surfaces and min-max problems in complete electrostatic systems:\\N\\NTheorem. Consider a complete electrostatic system \\((M,g,V,E)\\) such that \\(\\Lambda+|E|^{2}>0\\). Let \\(\\Omega_1, \\Omega_2\\) be connected maximal regions where \\(V\\neq 0\\), such that \\(\\Omega_i\\) is compact and let \\(\\Sigma=\\partial\\Omega_1 \\cap \\partial\\Omega_2 \\subset V^{-1}(0)\\) be unstable. Suppose \\(\\partial\\Omega_i \\setminus \\Sigma\\) is either empty or strictly stable, for \\(i = 1, 2\\). Then \\(\\Sigma\\) is the solution of a one-parameter min-max problem for the area functional in \\((M, g)\\) and has index equal to one.\\N\\NTheorem. Consider a complete electrostatic system \\((M, g, V, E)\\), such that \\(\\Lambda + |E|^2 > 0\\). Let \\(\\Omega_1, \\Omega_2\\) be connected maximal regions where \\(V\\neq 0\\), such that \\(\\Omega_i\\) is compact and let \\(\\Sigma=\\partial\\Omega_1 \\cap \\partial\\Omega_2 \\subset V^{-1}(0)\\) be unstable. Suppose that \\(\\partial(\\Omega_1 \\cup \\Omega_s)\\) is non empty and stable, and at least one of its components is degenerate. 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