{"entities":{"Q6674522":{"pageid":14393877,"ns":120,"title":"Item:Q6674522","lastrevid":84870788,"modified":"2026-06-02T15:33:00Z","type":"item","id":"Q6674522","labels":{"en":{"language":"en","value":"quantum Hamiltonian (normal mode, anharmonic)"}},"descriptions":{"en":{"language":"en","value":"quantum-mechanical represention of molecular normal modes of vibration beyond the harmonic approximation"}},"aliases":{},"claims":{"P989":[{"mainsnak":{"snaktype":"value","property":"P989","hash":"0ee6509aa8a85edbf37e5c789fcb9a1b444ec67e","datavalue":{"value":"\\hat{H} \\equiv \\frac{1}{2}\\sum_{i=1}^{3N-6}\\omega_i\\left(\\hat{p}_i^2+\\hat{q}_i^2\\right) + \\frac{1}{6} \\sum_{ijk} \\phi_{ijk} q_iq_jq_k + \\frac{1}{24} \\sum_{ijkl} \\phi_{ijkl} q_iq_jq_kq_l","type":"string"},"datatype":"math"},"type":"statement","id":"Q6674522$451E3BF0-8B1A-4513-98F7-14339137A8E1","rank":"normal"}],"P983":[{"mainsnak":{"snaktype":"value","property":"P983","hash":"bae95a6a3cf768818d2f0f4c4db8487986c0a282","datavalue":{"value":"N","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"d7a20b204fc378e1e511930537e60bd07701edc3","datavalue":{"value":{"entity-type":"item","numeric-id":6673745,"id":"Q6673745"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$FCABC653-779C-4D01-8AB5-A931535671BD","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"a28ff539da71afa7875314e9827e5ff0e6367eaf","datavalue":{"value":"\\omega","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"b8d9d843447567316c0108230532542193a3ffe0","datavalue":{"value":{"entity-type":"item","numeric-id":6673747,"id":"Q6673747"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$734501C0-A419-45E3-884D-A65FBF2BBA64","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"276120e646ab3d566a80037b03653e8533bc831a","datavalue":{"value":"\\phi_{ijkl}","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"8943d92f9604f18ce9ad01553f752fb8284d0ace","datavalue":{"value":{"entity-type":"item","numeric-id":6673744,"id":"Q6673744"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$8613BA3A-C1F4-4031-8C1A-4E51FD705CCA","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"a0066690db3725d9c5bcfd5496ecfbe02d1353c1","datavalue":{"value":"\\phi_{ijk}","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"8943d92f9604f18ce9ad01553f752fb8284d0ace","datavalue":{"value":{"entity-type":"item","numeric-id":6673744,"id":"Q6673744"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$113EC612-2561-4060-AFC7-63C318B2F265","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"72479055482acd9fba4ab419644abbef27017800","datavalue":{"value":"\\hat{p}","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"35f54908537f154a5578543c2b5815d8c4c6a1fe","datavalue":{"value":{"entity-type":"item","numeric-id":6674079,"id":"Q6674079"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$5491C06B-14D7-48EC-B8CB-F1ECF96BBC53","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"066956dfdebf112d5a463d4d33552855f4f423cb","datavalue":{"value":"\\hat{q}","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"c39d7842ee5bd9f077640db15891b16d38d2602d","datavalue":{"value":{"entity-type":"item","numeric-id":6674077,"id":"Q6674077"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$1BDF95AC-7BCD-4445-9346-7EB1AC676EA0","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P983","hash":"3dffa9301cf5655ccb40bd0c4c8639338d38a4dc","datavalue":{"value":"\\hat{H}","type":"string"},"datatype":"math"},"type":"statement","qualifiers":{"P984":[{"snaktype":"value","property":"P984","hash":"86b3430e94af339cc968b6fe99d929643b3fdcce","datavalue":{"value":{"entity-type":"item","numeric-id":6674522,"id":"Q6674522"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P984"],"id":"Q6674522$C90E73E1-AB6A-4291-AAE6-98B355166CF8","rank":"normal"}],"P1495":[{"mainsnak":{"snaktype":"value","property":"P1495","hash":"3829be87a43f9c3f931ee87cdfd749b2541f9f31","datavalue":{"value":{"entity-type":"item","numeric-id":6534265,"id":"Q6534265"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q6674522$C6CF0D84-38D3-44E2-81D6-71795B788B2D","rank":"normal"}],"P1460":[{"mainsnak":{"snaktype":"value","property":"P1460","hash":"1875e8e320782e4b36cdc4754053cd2d002a5f71","datavalue":{"value":{"entity-type":"item","numeric-id":6534271,"id":"Q6534271"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q6674522$D49162CD-76CE-4A47-9259-52C93DC913C6","rank":"normal"}],"P1684":[{"mainsnak":{"snaktype":"value","property":"P1684","hash":"01b1fb9cd9d1074d497d71a959721f21f351e923","datavalue":{"value":{"entity-type":"item","numeric-id":6674524,"id":"Q6674524"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q6674522$9DDB32E5-88AA-48F7-97C4-B07894B5FE48","rank":"normal"}],"P558":[{"mainsnak":{"snaktype":"value","property":"P558","hash":"8d52b0f65944829e68dc038fc85d942c53cb3e95","datavalue":{"value":{"entity-type":"item","numeric-id":6481547,"id":"Q6481547"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q6674522$168b8fa3-44b5-5ba6-ef08-fef5f54ccd51","rank":"normal"}],"P31":[{"mainsnak":{"snaktype":"value","property":"P31","hash":"d358c2b5b5cc063d8149b8355ca667f87fc03058","datavalue":{"value":{"entity-type":"item","numeric-id":6534237,"id":"Q6534237"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q6674522$625E1B06-4335-48B9-BC9B-3433F65E4E80","rank":"normal"}]},"sitelinks":{"mardi":{"site":"mardi","title":"Quantum Hamiltonian (normal mode, anharmonic)","badges":[],"url":"https://portal.mardi4nfdi.de/wiki/Quantum_Hamiltonian_(normal_mode,_anharmonic)"}}}}}