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Let \\(I \\subset S\\) be a homogeneous polynomial and \\(P \\in \\operatorname{Ass} R/I\\). Then the \\(v\\)-number \\(v_P(I)\\) of \\(I\\) with respect to \\(P\\) is defined by \\(v_P(I) = \\min \\{ \\deg f | I:_S f = P\\}\\) and \\(v(I) = \\min \\{v_P(I) | P \\in \\operatorname{Ass} S/I\\}\\). In recent research the \\(v\\)-numbers play a significant r\u00f4le. In the present paper the authors study the \\(v\\)-numbers of Stanley-Reisner rings in terms of its Alexander dual complex. The main results are: (1) The \\(v\\)-number of a cover ideal is just two less than the initial degree of its syzygy module. It provides a useful formula for cover ideals of finite simple graphs. (2) The authors prove some relation between the \\(v\\)-number of the Stanley-Reisner ideal and the Serre-depth of the quotient ring of the second symbolic power of the Stanley-Reisner ideal of its Alexander dual. 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