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(2) What is the sufficient and necessary condition on closed integral \\(3\\)-forms for the existence of prequantization \\(S^1\\) central extensions with pseudo-connections?\\N\\NIn the paper, an answer to these questions is given. A category \\(\\mathcal{D} \\mathcal{C}_{\\mathrm{ex}, 3-1}^3({G})\\) of degree \\(3\\) differential characters of a Lie groupoid \\(G\\) is described. Let Preq be a prequantization functor from it to the category \\(\\operatorname{Gerb}_{\\nabla}({G})\\) of \\(S^1\\)-central extensions with pseudo-connections over \\(G\\). It is shown that Preq is an equivalence of categories, and the isomorphism classes of \\(S^1\\)-central extensions with pseudo-connections over \\(G\\) are classified. Then, the characterization is given for closed integral \\(3\\)-forms with prequantization \\(S^1\\)-central extensions and pseudo-connections for all Lie groupoids. Moreover, the group of flat \\(S^1\\)-central extensions over a Lie groupoid \\(G\\) is identified with \\(H^2\\left(C_{\\mathrm{ex}}^*({G}, \\mathbb{R} / \\mathbb{Z})\\right)\\), the cohomology of a modification of the complex of singular cochains with coefficient in \\(\\mathbb{R} / \\mathbb{Z}\\). 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