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The proper power graph \\(\\mathcal{P}^\\ast(G)\\) is the simple undirected graph whose vertex set is \\(G^\\ast := G \\setminus \\{e\\}\\), and where two distinct vertices are adjacent if one is a power of the other. This paper investigates the domination number \\(\\gamma(\\mathcal{P}^\\ast(G))\\), defined as the cardinality of a smallest subset \\(D \\subseteq G^\\ast\\) such that every vertex in \\(G^\\ast \\setminus D\\) is adjacent to some vertex in \\(D\\). The focus is on structural and quantitative aspects of \\(\\gamma(\\mathcal{P}^\\ast(G))\\), particularly for nilpotent groups and direct products.\\N\\NThe authors first establish general lower and upper bounds for \\(\\gamma(\\mathcal{P}^\\ast(G))\\) in terms of the number of subgroups of prime order in \\(G\\). In the case where \\(G\\) is a finite \\(p\\)-group, the domination number coincides with the number of subgroups of order \\(p\\).\\N\\NNext, they sharpen the upper bound for nilpotent groups by introducing a subset \\(B\\) of prime divisors \\(\\pi(G)\\) for which the corresponding Sylow subgroup contains a unique maximal cyclic subgroup for some element of prime order. Under this condition, a refined upper bound is proved that can improve the general one.\\N\\NThe third main result concerns direct products: for \\(G = H \\times K\\), they prove that \\(\\gamma(\\mathcal{P}^\\ast(G)) \\ge \\gamma(\\mathcal{P}^\\ast(H)) + \\gamma(\\mathcal{P}^\\ast(K)) - 1\\), with equality characterized by the existence of prime order elements lying in unique maximal cyclic subgroups.\\N\\NThe final sections apply the theory to compute exact values of \\(\\gamma(\\mathcal{P}^\\ast(G))\\) for various classes of nilpotent groups, including generalized quaternion groups, direct products with cyclic groups, and groups of order divisible by two 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