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this paper, the authors complete the classification of one-dimensional components in the K-moduli space \\(M_3^{\\mathrm{Kps}}\\) of K-polystable smoothable Fano \\(3\\)-folds. Based on the classical Iskovskikh-Mori-Mukai classification, there are \\(105\\) deformation families of smooth Fano \\(3\\)-folds. While \\(27\\) of these families contain no K-polystable smooth \\(3\\)-folds, the general element of the remaining \\(78\\) families is K-polystable. Working inductively on the dimension of the moduli components, the authors note that \\(20\\) of these families contain a unique K-polystable smooth object, corresponding to zero-dimensional K-moduli spaces. This paper focuses on the next step: analyzing \\(6\\) of the \\(8\\) families of smooth Fano \\(3\\)-folds with one-dimensional moduli that contain K-polystable elements. These \\(6\\) families correspond to the Mori-Mukai notations \\(2.24\\), \\(2.25\\), \\(2.22\\), \\(3.12\\), \\(4.13\\), and \\(3.13\\). The authors explicitly parameterize these families and introduce their singular limits (denoted by \\(X_\\infty\\) or \\(X'_\\infty\\)). The Main Theorem establishes the K-polystability of these singular limits for families \\(2.22\\), \\(3.12\\), \\(4.13\\), and \\(3.13\\). Combined with results in [\\textit{C. Araujo} et al., The Calabi problem for Fano threefolds. Cambridge: Cambridge University Press (2023; Zbl 1536.14032)], the authors prove that all one-dimensional components of \\(M_3^{\\mathrm{Kps}}\\) are isomorphic to \\(\\mathbb{P}^1\\). To prove the K-polystability of these singular \\(3\\)-folds, the authors apply a powerful criterion due to \\textit{Z. Zhuang} [Invent. Math. 226, No. 1, 195--223 (2021; Zbl 1483.14076)]. The argument also relies on the inductive argument of \\textit{H. Abban} and \\textit{Z. Zhuang} [Forum Math. Pi 10, Paper No. e15, 43 p. (2022; Zbl 1499.14066)]. Another interesting observation is that for Family \\(3.13\\), which consists of complete intersections of three divisors in \\(\\mathbb{P}^2 \\times \\mathbb{P}^2 \\times \\mathbb{P}^2\\), the singular K-polystable limit \\(X'_\\infty\\) is no longer a complete intersection, demonstrating that a K-moduli space may not coincide with the GIT 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