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Using these methods an index theorem for this class of deformations is obtained.   A Lie algebroid is a vector bundle \\(E\\) over \\(M\\) whose sheaf of sections is a sheaf of Lie algebras, and a morphism of bundles \\(\\rho:E\\to TM\\) satisfying \\(\\rho[\\xi,\\eta]= [\\rho(\\xi), \\rho(\\eta)]\\) and \\([f\\xi,\\eta]= f[\\xi,\\eta]- L_{\\rho(\\eta)}(f)\\xi\\), \\(f\\in C^\\infty(M)\\), \\(\\xi,\\eta\\in \\Gamma(M, E)\\). One defines \\(E\\)-differential forms as elements of \\(\\Gamma(M,\\Lambda E^*)\\), and introduces the de Rham differential using the Cartan formula. A symplectic Lie algebroid is a Lie algebroid with a nondegenerate closed \\(2\\)-\\(E\\)-differential form. Examples of symplectic Lie algebroids are: symplectic manifolds, constant rank Poisson structures, symplectic structures with logarithmic singularities along submanifolds of codimension one, manifolds with corners, compactified cotangent bundles, complex symplectic manifolds.   A deformation is a formal power series \\(\\overline\\omega= \\sum_{k\\geq 0}(i\\hslash)^k P_k\\), where \\(P_k\\) are \\(E\\)-bidifferential operators, \\(P_0(f, g)= fg\\) and \\(P_1(f,g)- P_1(g, f)= \\{f,g\\}\\).   The main classification results of the paper are   Theorem 1.1. Let \\((E,[,],\\rho,\\omega)\\) be a symplectic Lie algebroid on \\(M\\). The set \\(\\mathbb{A}^{\\hslash}(M)\\) of isomorphism classes of \\(E\\)-deformations of \\((E,[,],\\rho,\\omega)\\) is an bijective correspondence with the space  \\[ {1\\over i\\hslash} \\omega+{^E H^2}(M, \\mathbb{C}[[\\hslash]]), \\]  where \\({^EH^2}(M,\\mathbb{C}[[\\hslash]])\\) is the second cohomology group of the \\(E\\)-de Rham complex. The cohomology class \\(\\theta\\) associated to the deformation by the above theorem is called its characteristic class.   Theorem 1.2. Let \\(\\mathbb{A}^{\\hslash}(M)= (C^\\infty(M)[[\\hslash]],*)\\) be an \\(E\\)-deformation of \\(M\\). There exists a Lie algebra extension  \\[ 0\\to \\text{Ad}(\\mathbb{A}^{\\hslash}(M))\\to {^E\\text{Der}}(\\mathbb{A}^{\\hslash}(M))\\to {^EH^1}(M, \\mathbb{C}[[\\hslash]])\\to 0. \\]  A deformation of a complex manifold \\(M\\) is a structure of a sheaf of algebras on \\({\\mathcal O}_M[[\\hslash]]\\) which is equal to \\({\\mathcal O}_M\\) modulo \\(\\hslash\\) and such that the local multiplication law and the transition isomorphisms are given by power series in \\(\\hslash\\) with coefficients in bidifferential operators. Given a complex manifold \\(M\\), let \\(F^* \\Omega^{*,*}\\) denote the decreasing filtration of the de Rham complex  \\[ F^i \\Omega^{*,*}(M)= \\sum_{0\\leq k,l\\leq i}\\Omega^{(k,l)}(M). \\]  The classification result for complex manifolds is   Theorem 1.3. Let \\((M,\\omega)\\) be a complex manifold with a holomorphic symplectic structure \\(\\omega\\), such that the maps  \\[ H^i(M,\\mathbb{C})\\to H^i(M,{\\mathcal O}_M);\\quad i= 1,2 \\]  are surjective. The set of isomorphism classes of formal deformations of \\((M,\\omega)\\) is in bijective correspondence with \\(H^2(F^1\\Omega^{*,*}(M), d)[[\\hslash]]\\). Moreover, there exists a family of smooth maps  \\[ \\tau: \\{H^2(F^1\\Omega^{*,*}(M), d)\\}^n\\to H^2(M,{\\mathcal O}_M) \\]  such that the characteristic class of the deformation associated to \\(\\alpha_0+ \\hslash\\alpha_1+\\cdots\\) is given by the sum  \\[ {1\\over i\\hslash} \\omega+ \\sum_n \\hslash^n(\\alpha_n+ \\tau_n(\\alpha_0,\\dots, \\alpha_{n- 1})). \\]  The associated formal deformation of the sheaf of algebras of holomorphic functions is locally isomorphic to the Weyl deformation of holomorphic functions on an open polydisk in \\(\\mathbb{C}^{\\dim M}\\).   The basic tool used in the proofs is the notion of \\(E\\)-jets, a generalization of the notion of infinite jets of smooth functions. In the last section of the paper the authors prove an index theorem which is a consequence of the Riemann-Roch theorem for periodic cyclic 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