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M. Wood} [Adv. Math. 226, No. 2, 1756--1771 (2011; Zbl 1262.11049)] established a set-theoretical bijection between isomorphism classes of primary binary quadratic forms over such a scheme \\(\\mathcal S\\) and isomorphism classes of pairs \\((\\mathcal C,\\mathcal M)\\), where \\(\\mathcal C\\) is a quadratic algebra over \\(\\mathcal S\\) (that is, a locally free \\(\\mathcal O_{\\mathcal S}\\)-algebra of rank 2, where \\(\\mathcal O_{\\mathcal S}\\) denotes the structure sheaf of \\(\\mathcal S\\)) and \\(\\mathcal M\\) is an invertible \\(\\mathcal C\\)-module. The approach here is to recover from Wood's bijection an explicit bijection between the Picard group of the quadratic algebra and a set of classes of primitive quadratic forms over \\(\\mathcal S\\). An important preliminary step is to establish a classification of quadratic algebras over \\(\\mathcal S\\), which is achieved here by using two invariants, the discriminant and the parity. For this purpose, a scheme-theoretic version of the notion of parity introduced over \\(\\mathbb Z\\) by \\textit{J. Towber} [Adv. 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