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This notion goes back to 1930's papers by \\textit{I. Schoenberg} [Math. Z. 32, 321--328 (1930; JFM 56.0106.06)] and by \\textit{F. Gantmacher} and \\textit{M. Krein} [C. R. Acad. Sci., Paris 201, 577--579 (1935; Zbl 0012.28903)]. In 1994 \\textit{G. Lusztig} generalized total positivity to the context of general split real semisimple (resp. reductive) Lie groups [Prog. Math. 123, 531--568 (1994; Zbl 0845.20034)]. Such notion plays an important role in representation theory and has relations to other areas in mathematics as well as to problems in theoretical physics. In recent years, total positivity was also applied in the context of higher Teichm\u00fcller theory.\\N\\NIn this article, the notion of \\(\\Theta\\)-\\textit{positivity} is introduced. It generalises at the same time Lusztig's total positivity in split real Lie groups as well as well-known concepts of positivity in Lie groups of Hermitian type, related to bi-invariant orders and causality. The \\(\\Theta\\)-positivity depends on the choice of a flag variety associated with the group \\(G\\), which is determined by a subset \\(\\Theta\\) of the set of simple roots (when the group is split, the flag variety is the complete flag variety; for the Lie groups of Hermitian type, the flag variety is the Shilov boundary).\\N\\NDenote by \\(P_\\Theta\\) the parabolic subgroup determined by \\(\\Theta\\), by \\(U_\\Theta\\) its unipotent radical and by \\(F_\\Theta=G/P_\\Theta\\) the corresponding flag manifold. The group \\(L_\\Theta=P_\\Theta\\cap P_\\Theta^{\\mathrm{opp}}\\) acts on the Lie algebra \\(\\textbf{u}_\\Theta\\) by the adjoint action and for every \\(\\alpha\\in \\Theta\\) there is an irreducible piece \\(\\textbf{u}_\\alpha\\). One says that \\(G\\) admits a positive structure relative to \\(\\Theta\\) if for every root \\(\\alpha\\in\\Theta\\), there exists an acute convex cone \\(c_\\alpha \\subset \\textbf{u}_\\alpha\\) that is invariant under the action of the connected component \\(L^0_\\Theta\\) of \\(L_\\Theta\\).\\N\\NThe semisimple Lie groups admitting a \\(\\Theta\\)-positive structure are classified and the fundamental properties of \\(\\Theta\\)-positivity are investigated. Besides split real Lie groups and Lie groups of Hermitian type, there are exactly two other families admitting \\(\\Theta\\)-positive structures, namely groups locally isomorphic to \\(\\mathrm{SO}(p, q)\\), for \\(p\\not=q\\) and the exceptional family of real forms of \\(F_4\\), \\(E_6\\), \\(E_7\\), \\(E_8\\), whose restricted root system is of type \\(F_4\\).\\N\\NFor a group \\(G\\) admitting a positive \\(\\Theta\\)-structure, the non-negative unipotent semigroup is defined as \\(U_\\Theta^{\\ge 0}:=\\bigcup_{\\alpha\\in \\Theta}\\exp(c_\\alpha)\\) and the positive semigroup \\(U_\\Theta^{>0}\\) as the interior of \\(U_\\Theta^{\\ge 0}\\) (relative to \\(U_\\Theta\\)). An explicit parametrisation of the positive semigroup \\(U_\\Theta^{>0}\\) and the tangent cone at the identity of the non-negative cone \\(U_\\Theta^{\\ge 0}\\) are then obtained.\\N\\NThe positive unipotent semigroups \\(U_\\Theta^{>0}\\) are later used to define positive \\(n\\)-tuples in the flag variety \\(F_\\Theta\\). This allows the notion of positive representations of surface groups. Several results of this paper have been used to prove the conjecture that the set of positive representations form higher rank Teichm\u00fcller 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