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In particular, it is applicable to the Dirac operator with multi-centre Coulomb potential   \\[  H = c \\hbar \\sum_{j=1}^3 \\alpha \\mathbb P+ mc^2 \\beta+ \\gamma \\sum_{k=1}^n \\frac{z_k}{|x-a_k|}  \\]   describing a spin \\(1/2\\)-particle in the electric field of charges \\(z_k\\) at position \\(a_k\\).  \\noindent Under some conditions on the potential \\(V\\), the resolvent \\((H - z)^{-1}\\) can be written as a block operator matrix whose entries are Schr\u00f6dinger like operators which depend on \\(z\\). 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