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In the case when \\(C_i=k\\), for all \\(v_i\\in Q_0\\), we have \\(k(Q^c,\\mathcal C)=kQ^c\\), the usual path coalgebra associated to \\(Q\\), and this justifies the terminology. On the other hand, for \\(G\\) a finite group and \\(r\\) a ramification data of \\(G\\), that is an element of \\(\\mathbb N^{\\mathcal D}\\) where \\(\\mathbb N\\) is the set of positive integers and \\(\\mathcal D\\) is the set of conjugacy classes of \\(G\\), one can associate the Hopf quiver \\(Q(G,r)\\).   The main aim of the paper is to give conditions under which \\(k(Q^c,\\mathcal C)\\) admits a Hopf structure. 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