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Here, \\((S, d)\\) is a metric space, \\(\\text{Lip}(S)\\) the space of all real-valued Lipschitz functions on \\(S\\) with Lipschitz semi-norm \\(|f|_{\\text{Lip}}\\), \\(BL(S)\\) the Banach space of bounded Lipschitz functions with norm \\( \\| f \\|_{BL} =\\|f \\|_{\\infty} +|f|_{\\text{Lip}}\\), and \\(\\text{Lip}_{e}(S)\\) the Banach space when \\(\\text{Lip}(S)\\) is given the norm \\( \\|f \\|_{e} = |f(e)| + |f|_{\\text{Lip}}\\) for an \\( e \\in S\\). \\( \\mathcal{M}(S)\\) is the vector space of all bounded Borel measures on \\(S\\), and \\(\\mathcal{M}_{1}(S) =\\{\\mu \\in \\mathcal{M}(S): \\int d(x,e) d |\\mu| (x) < \\infty \\} \\) with the norm \\(\\| \\mu \\|_{1}= \\int \\max(1, d(x,e))\\;d |\\mu| (x)\\). \\(\\mathcal{S}_{BL}\\) is the closure of the linear space of discrete Borel measure on \\(S\\) in \\(BL(S)^{\\ast}\\) and \\(\\mathcal{S}_{e}\\) is the closure of the linear space of discrete Borel measure on \\(S\\) in \\(\\text{Lip}_{e}^{\\ast}\\); \\(\\mathcal{S}_{BL}^{+}\\) is the closure of the cone of non-negative discrete Borel measure on \\(S\\) in \\(BL(S)^{\\ast}\\) and \\(\\mathcal{S}_{e}^{+}\\) is the closure of the cone of non-negative discrete Borel measure on \\(S\\) in \\(\\text{Lip}_{e}^{\\ast}\\). A \\(\\mu \\in \\mathcal{M}(S)\\) is called separable if there is a separable Borel set \\(B \\subset S\\) such that \\( |\\mu|(S \\setminus B) =0\\); \\( \\mathcal{M}_{s}(S)\\) is the set of all separable measures.  \\(\\text{Lip}(S, S)\\) is the space of Lipschitz maps \\(\\Phi: (S, d) \\to (S, d) \\). \\( (\\Phi_{t})_{t \\geq 0} \\subset \\text{Lip}(S, S)\\), satisfying the conditions \\( \\Phi_{t} \\circ \\Phi_{s}= \\Phi_{t+s}, \\; \\Phi_{0}=\\text{Id}_{S}\\), is called a Lipschitz semigroup on \\(S\\). This Lipschitz semigroup is called strongly continuous if \\( t \\to \\Phi_{t}(x)\\) is continuous for all \\(x \\in S\\). A Lipschitz semigroup \\( (\\Phi)_{t \\geq 0}\\) gives rise to a semigroup of bounded linear operators \\( (S_{\\Phi}(t))_{t \\geq 0}\\) , \\(S_{\\Phi}(t): \\text{Lip}_{e}(S) \\to \\text{Lip}_{e}(S), \\; S_{\\Phi}(t)(f)= f \\circ \\Phi_{t}\\); this semigroup gives the semigroup of dual operators \\( (S_{\\Phi}^{\\ast}(t))_{t \\geq 0}\\), which further gives a semigroup of bounded linear operators \\( (\\Hat{T}_{\\Phi}(t))_{t \\geq 0}\\), \\(\\Hat{T}_{\\Phi}(t): \\mathcal{S}_{e} \\to \\mathcal{S}_{e}, \\; \\Hat{T}_{\\Phi}(t) \\varphi = S_{\\Phi}^{\\ast}(t) \\varphi\\).  Many results are proved about the relations between these sets and mappings. The following are some of the results:  (i) \\(\\mathcal{S}_{e}^{\\ast} \\) is isometrically isomorphic to \\(\\text{Lip}_{e}(S)\\) and \\(\\mathcal{S}_{BL}^{\\ast} \\) is isometrically isomorphic to \\(BL(S)\\).  (ii) \\(\\mathcal{M}_{s}^{+} \\subset \\mathcal{S}_{BL}^{+}\\) and \\(\\mathcal{M}_{s}^{+} = \\mathcal{S}_{BL}^{+}\\) iff \\(S\\) is complete. \\(\\mathcal{M}_{s, 1}^{+} \\subset \\mathcal{S}_{e}^{+}\\) and \\(\\mathcal{M}_{s}^{+} = \\mathcal{S}_{e}^{+}\\) iff \\(S\\) is complete.  (iii) \\( \\mathcal{S}_{BL} \\cap BL(S)^{\\ast}_{+}= {S}_{BL}^{+}\\) and \\( \\mathcal{S}_{e} \\cap \\text{Lip}_{e}(S)^{\\ast}_{+} = \\mathcal{S}_{e}^{+}\\).  (iv) For every \\( x, y \\in S\\) and every \\( s, t \\geq 0\\), \\(d( \\Phi_{s}(x), \\Phi_{t}(y)) = \\| \\Hat{T}_{\\Phi}(s) \\delta_{x} - \\Hat{T}_{\\Phi}(t) \\delta_{y} \\|_{e}^{\\ast}\\). Also, some equivalent characterizations of strong continuity of \\( (\\Hat{T}_{\\Phi}(t))_{t \\geq 0}\\) on \\(\\mathcal{S}_{e}\\), in terms of strong continuity of \\( (\\Phi_{t})_{t \\geq 0}\\) and some other conditions, are 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