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An element \\(\\phi\\) of \\(S_H(A)\\) is said to be \\(C^*\\)-extreme if, whenever \\(\\phi=\\sum^n_{i=1}t^*_i\\phi_i(\\cdot)t_i\\) with invertible \\(t_i\\) in \\(B(H)\\) and \\(\\sum t^*_it_i=1\\), then each \\(\\phi_i\\) is unitarily equivalent to \\(\\phi\\) (i.e., there is a unitary \\(u \\in B(H)\\) such that \\(\\phi (.) = u \\phi_i (.)u\\)).  The general properties of \\(C^*\\)-extreme points in \\(S_H (A)\\) were studied by \\textit{D.\\,R.\\thinspace Farenick} and \\textit{P.\\,B.\\thinspace Morenz} in [Trans.\\ Am.\\ Math.\\ Soc.\\ 349, No.\\,5, 1725--1748 (1997; Zbl 0873.46030)] who established a complete description of the set of \\(C^*\\)-extreme points in \\(S_H (A)\\) in each of the following cases: {\\parindent6mm \\begin{itemize}\\item[(a)] \\(S_{\\ell_2^2}(A)\\), where \\(A\\) is arbitrary; \\item[(b)] \\(S_{\\ell_2^r}(A)\\), where \\(A\\) is commutative;  \\item[(c)] \\(S_{\\ell_2^r}(M_{n})\\).   \\end{itemize}} The description obtained in case (b) shows that if \\(H\\) has finite dimension, then an element \\(\\phi\\) in \\(S_{H} ( C(X))\\) is a C\\(^*\\)-extreme point if and only if \\(\\phi\\) is multiplicative. It is also proved that C\\(^*\\)-extreme points of \\(S_{H}(C(X))\\) need not be multiplicative when \\(H\\) is infinite-dimensional. In general, every multiplicative generalised state \\(\\phi\\in S_{H}(C(X))\\) is a C\\(^*\\)-extreme point, independently of the dimension of \\(H\\).  The paper under review presents new advances in the study of \\(C^*\\)-extreme points in \\(S_H (C(X))\\). The main result (Theorem 5) gives a new necessary condition for a map \\(\\phi\\) in \\(S_{H} (C(X))\\) to be a C\\(^*\\)-extreme point. Indeed, given \\(\\phi\\in S_{H}(C(X))\\), let \\(\\mu_\\phi\\) denote the unique positive operator-valued measure associated with \\(\\phi\\) (that is, \\(\\phi(f)=\\int_X f \\,d\\mu_\\phi\\), for all \\(f\\in C(X)\\)). If \\(\\phi\\) is a C\\(^*\\)-extreme point of \\(S_{ H}(C(X))\\), then for every Borel subset \\(F\\subseteq X\\) the operator \\(\\mu_\\phi(F)\\) is either a projection, necessarily commuting with \\(\\phi(C(X))\\), or \\(\\sigma(\\mu_\\phi(F))=[0,1]\\).  As a consequence of this result, the author gives a new and shorter proof of the fact, established by Farenick and Morenz, that \\(C^*\\)-extreme points of \\(S_{\\ell_2^r}(C(X))\\) are \\(^*\\)-homomorphisms. Another consequence shows that C\\(^*\\)-extreme operators from \\(C(X)\\) into \\(\\mathcal{K}^+\\), the algebra generated by the compact and scalar operators on an arbitrary complex Hilbert space \\(H\\), are multiplicative.  The problem of finding a complete characterisation of the \\(C^*\\)-extreme points of \\(S_{H}(C(X))\\), for an arbitrary complex Hilbert space \\(H\\), remains 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