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Existence, characterization, (strong) uniqueness, and discretization results are given, along with several examples. It is also shown that if \\(n\\geq 1\\), then approximation on \\([0,\\infty)\\) is equivalent to approximation on [0,b] for some real b; b can be determined constructively. For the corresponding results in the case where only the coefficient of \\(x^ n\\) is required to be nonnegative, see the authors, Approximation on subsets of \\([0,\\infty)\\) by reciprocals of polynomials, Approximation Theory IV, Academic Press, 553- 559 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