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If f and g are two real-valued functions with domains contained in R, the real numbers, and \\(c\\in R\\), let \\(f+g\\), fg, cf, \\(f\\circ g\\), f/g denote the usual pointwise operations of addition, multiplication, scalar multiplication, composition and division, each defined on its natural domain (the largest set on which the resulting formula makes sense). Let F denote any set of real-valued functions with non-empty domains contained in R satisfying the following properties. 1. F is closed under addition, multiplication and scalar multiplication. 2. If f and g are in F, then \\(f\\circ g\\) and f/g are also in F whenever their natural domains are non-empty. 3. i(x)\\(\\equiv x\\) and u(x)\\(\\equiv 1\\) are in F. Observe that any such F is an algebra of real-valued functions which contains the rational functions. A chain rule operator on F is a linear operator, D, on F such that if \\(f\\circ g\\in F\\) and (Df)\\(\\circ g\\in F\\), then \\(D(f\\circ g)=((Df)\\circ g)(Dg)\\). Any linear operator, P, on F which satisfies \\(P(fg)=(Pf)g+f(Pg)\\) is called a derivation. The major goal of the paper is given by the theorem: Any chain rule operator on F is a derivation on F. The proof of that is based on the lemma, in which a symbol s denotes function \\(s(x)=x^ 2:\\) If D is a chain rule operator which is not the zero operator, then a) \\(Di=u\\), b) \\(Du=0\\), c) \\(Ds=ki\\) for some \\(k\\in R\\). From the mentioned theorem there are two more following corollaries: 1. If D is a chain rule operator on F, then a) \\(D(f/g)=((Df)g-f(Dg))/(s\\circ g)\\) whenever f/\\(g\\in F\\), b) \\((Df^{-1})(f(x))=1/(Df)(x)\\) provided (Df)(x)\\(\\neq 0\\). 2. Suppose F contains all the elementary functions and D is a non-trivial chain rule operator such that if \\(f\\in F\\) is differentiable at \\(x\\in R\\), then x is in the domain of Df. Then \\(De=de/dx\\) whenever e is an elementary 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