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The isolated singularity is called smoothable if there is a flat family \\(\\phi: {\\mathcal V}\\to D\\) over the unit disk D such that \\(\\phi^{-1}(0)\\) is isomorphic to V and the generic fibre of \\(\\phi\\) is non-singular. Examples of non-smoothable isolated singularities have been detected by complex cobordism (first used by R. Thom for this purpose) by studying the link of the singularity, i.e. the intersection of V and the boundary \\(S_{\\epsilon}^{2N-1}\\) of a small ball \\(B_{\\epsilon}\\) about the singular point of V embedded in \\({\\mathbb{C}}^ N\\). \\textit{E. Looijenga} and \\textit{J. Wahl} [Topology 25, 261-291 (1986; Zbl 0615.32014)] showed that invariants of the linking pairing on the link of the singularity could also be used to detect non-smoothability.    The main result of the present paper is to show that Rokhlin's \\(\\mu\\)- invariant can also be used to detect non-smoothability for surface singularities. The connection is as follows. If \\(\\dim (V,0)=2\\), then the link of \\(0\\in V\\) is a closed 3-manifold which may be regarded as the boundary of a resolution \\(\\tilde V\\) of the singularity. If \\((V,0)\\) is ``Gorenstein'', meaning that (V,0) is normal and there exists a nonzero holomorphic 2-form \\(\\omega\\) on \\(V-\\{0\\}\\), then \\((\\tilde V,\\partial \\tilde V)\\) inherits a spin structure on the complement \\(\\tilde V-S\\) of a (real) 2-dimensional closed surface \\(S\\subset \\tilde V\\) representing the Poincar\u00e9 dual of \\(w_ 2(\\tilde V)\\). The spin structure allows one to define a quadratic form \\(q: H_ 1(S,{\\mathbb{Z}}/2)\\to {\\mathbb{Z}}/2\\), whose Arf invariant is denoted Arf(S). Then the \\(\\mu\\)-invariant \\(\\mu (\\partial \\tilde V)\\equiv \\frac{1}{8}(\\sigma (\\tilde V)-S^ 2)+Arf(S)\\) (mod 2), where \\(\\sigma(\\tilde V)\\) denotes the signature of \\(\\tilde V\\) and \\(S^ 2\\) the self-intersection of the homology class represented by S in \\(\\tilde V\\) (note that the formula in the lemma, {\\S}1, has a misprint).    Theorem 1. Let \\((V,0)\\) be a 2-dimensional smoothable Gorenstein singularity. Let \\(\\tilde V\\) be a resolution with canonical class K and S a smooth (real) surface in \\(\\tilde V\\) dual to \\(K\\;(\\bmod 2)\\). Then \\(K^ 2+8p_ g=S^ 2+8Arf(S)\\) (mod 16), where \\(p_ g\\) is the geometric genus of \\(\\tilde V.\\)    A corollary (theorem 2) gives a condition for smoothability in terms of the configuration of exceptional curves. Explicit examples of isolated singularities violating this condition are given in {\\S}3 and the authors point out that the non-smoothability of these examples is not detected by previously studied 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