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The aim of this paper is to study a model of repeated interaction between quantum systems, which can be thought of as a non-commutative Markov chain. For Hilbert spaces \\({\\mathcal H}, {\\mathcal K}\\) and \\({\\mathcal P}\\), the unitary operator \\(U : {\\mathcal H} \\otimes {\\mathcal K}\\to{\\mathcal H} \\otimes {\\mathcal P}\\) is an interaction with vacuum vectors \\(\\Omega^{{\\mathcal H}} \\in {\\mathcal H}\\), \\(\\Omega^{{\\mathcal K}} \\in {\\mathcal K}\\), and \\(\\Omega^{{\\mathcal P}} \\in {\\mathcal P}\\) in the sense that \\(U(\\Omega^{{\\mathcal H}} \\otimes \\Omega^{{\\mathcal K}})=\\Omega^{{\\mathcal H}} \\otimes \\Omega^{{\\mathcal P}}\\), and for the unitary operators \\(U_{\\ell}\\) on \\({\\mathcal H} \\otimes {\\mathcal K}_{\\infty}\\) (with infinite tensor product \\({\\mathcal K}_{\\infty}=\\bigotimes_1^{\\infty} {\\mathcal K} )\\), \\(\\ell \\in {\\mathbb N}\\), being identical with \\(U\\) on \\({\\mathcal H} \\otimes {\\mathcal K}_{\\ell}\\), the repeated interaction up to time \\(n \\in {\\mathbb N}\\) is realized as   \\[  U(n) = U_n U_{n-1} \\cdots U_2 U_1 : {\\mathcal H} \\otimes {\\mathcal K}_{\\infty} \\to {\\mathcal H} \\otimes {\\mathcal P}_{[1,n]} \\otimes {\\mathcal K}_{[n+1. \\infty]}. \\]   The author considers the model of non-commutative Markov chains as a Markovian approximation of a repeated atom-field interaction by a physicist's point of view. It is shown that there exists an outgoing Cuntz scattering system \\(( {\\mathcal L}, \\underline{V} =( V_1, \\dots, V_d)\\), \\({\\mathcal G}_*^+\\), \\({\\mathcal G})\\) associated to this model which induces an input-output formalism with a transfer function corresponding to a multi-analytic operator, in the sense of multivariate operator theory, where \\(\\underline{V}\\) is a row isometry on the Hilbert space \\({\\mathcal L}\\), and \\({\\mathcal G}_*^+\\) and \\({\\mathcal G}\\) are subspaces of \\({\\mathcal L}\\) such that (i) \\({\\mathcal G}_*^+\\) is the smallest \\(\\underline{V}\\)-invariant subspace containing \\({\\mathcal E}_*:={\\mathcal L}\\ominus\\text{span}_{j=1, \\dots, d}\\) \\(V_j {\\mathcal L}\\), thus \\(\\underline{\\text{V}} | {\\mathcal G}_*^+\\) is a row shift and \\({\\mathcal G}_*^+=\\bigoplus_{ \\alpha \\in F_d^+} V_{\\alpha} {\\mathcal E}_*\\) with the free semigroup \\(F_d^+\\) with generators \\(1, \\dots, d\\), and \\(\\alpha \\in F_d^+\\) is the word \\(\\alpha_{\\ell} \\cdots \\alpha_1\\) of length \\(| \\alpha | = \\ell\\), with \\(\\alpha_j \\in\\{ 1,2, \\dots, d \\}\\); (ii) \\(\\text{\\underbar{V}} | {\\mathcal G}\\) is a row shift, thus \\({\\mathcal G}=\\bigoplus_{\\alpha \\in F_d^+} V_{\\alpha} {\\mathcal E}\\) with \\({\\mathcal E}:={\\mathcal G}\\ominus\\text{span}_{ j =1, \\dots, d} V_j {\\mathcal G}\\). Finally, the author shows that observability for this system is closely related to the scattering theory of non-commutative Markov chains [cf.\\ \\textit{B.\\,K\u00fcmmerer} and \\textit{H.\\,Maassen}, Infin.\\ Dimens.\\ Anal.\\ Quantum Probab.\\ Relat.\\ Top.\\ 3, No.\\,1, 161--176 (2000; Zbl 1243.81104)]. For other related works, see, e.g., \\textit{R.\\,Gohm, B.\\,K\u00fcmmerer}, and \\textit{T.\\,Lang} [Ergodic Theory Dyn.\\ Syst.\\ 26, No.\\,5, 1521--1548 (2006; Zbl 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