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As a consequence of more general results, \\textit{T. Breuer, L. H\u00e9thelyi, E. Horv\u00e1th, B. K\u00fclshammer}, and \\textit{J. Murray} [J. Algebra 296, No. 1, 177-195 (2006; Zbl 1121.20005)] have shown that \\(G\\) contains a real element of 2-defect zero if and only if \\(c_{ii}\\) is odd for some \\(i\\). Here the authors prove that in this case \\(i\\) can be chosen in such a way that \\(\\varphi_i\\) is real-valued. Also, the existence of a real element of 2-defect zero is equivalent to the existence of an odd Cartan invariant \\(c_{ij}\\) with real-valued \\(\\varphi_i\\) and \\(\\varphi_j\\). Examples seem to indicate that there is no connection to the existence of a \\(G\\)-invariant quadratic form on the relevant simple modules. The authors show also that for a group of even order the first Cartan invariant \\(c_{11}\\) corresponding to the trivial Brauer character is always 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