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Denote by \\(X_f\\) the set of smooth points of \\(f\\). One of the obtained main results is the following: if \\(f\\) is a PS function, then \\(X_f\\) is not locally connected around a point \\(x\\in O\\setminus X_f\\). Using this criteria one obtains that a large class of semismooth functions, like the \\(p\\)-norms functions, NCP functions, smoothing/penalty and integral functions are not PS functions. In connections with this property the authors introduced the concept of almost smooth functions (AS), namely a function \\(f\\) is AS function if for any \\(x\\in O\\setminus X_f\\), there is \\(\\varepsilon>0\\), such that \\(B_{\\overline{\\varepsilon}}(x)\\cap X_f\\) is connected for any \\(0<\\overline{\\varepsilon}<\\varepsilon\\). In addition there are introduced some variants of AS functions. 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