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In particular, results on the existence of precovers and preenvelopes under the functors \\(\\Hom_R(S,-)\\), \\(\\Hom_R(-,S)\\) and \\(-\\otimes_RS\\) are obtained. From these results, the behaviour of cotorsion (injective) precovers and preenvelopes under change of rings, as well as properties of flat (FP-injective) precovers and preenvelopes under localization of rings follow. In the final section, restrictions are placed on the \\(R\\)-homomorphism \\(R\\to S\\), such as surjectivity or being an (almost) excellent extension. 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