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The order is the number of lines of \\(B\\) passing through a general point of \\(\\mathbb P^n\\). Congruences of order one have proved to be interesting not only in projective algebraic geometry but also in the applications, for instance to the theory of systems of conservation laws [see \\textit{S. I. Agafonov, E. V. Ferapontov}, Manuscr. Math. 106, No. 4, 461--488 (2001; Zbl 1149.35385)]. The classification of these congruences in \\(\\mathbb P^3\\) has been performed classically by Kummer and concluded by \\textit{Z. Ran} [J. Reine Angew. Math. 368, 119--126 (1986; Zbl 0601.14042)].  The article under review is part of series devoted by the author to the classification of congruences of order one in \\(\\mathbb P^4\\). After classifying those with a fundamental curve [\\textit{P. De Poi}, Manuscr. Math. 106, No. 1, 101--116 (2001; Zbl 1066.14062)] and those with irreducible fundamental surface [\\textit{P. De Poi}, Math. Nachr. 278, No. 4, 363--378 (2005; Zbl 1070.14045)], here he gives a complete description of those whose focal locus \\(F\\), which carries a natural structure of scheme, is a generically non-reduced surface. If \\(F\\) is irreducible, a general line of \\(B\\) either intersects \\(F\\) in a fat point of length \\(3\\) or in \\(2\\) points, one of which is a fat point of length \\(2\\). In the first case \\(F_{red}\\) results to be a plane, and in the second one a non-degenerate cubic scroll. If \\(F\\) is reducible, then it splits in two components \\(F_1\\) and \\(F_2\\), the first one non-reduced and the other reduced, and there are the following possibilities: either \\((F_1)_{red}\\) is a plane and \\(F_2\\) is a rational non-degenerate surface, or \\(F_2\\) is a plane and \\((F_1)_{red}\\) is a non-degenerate rational scroll. 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