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Let \\(u\\) and \\(v\\) be the moment regular functionals associated with \\((P_n)_n\\) and \\((Q_n)_n\\) (resp.). Assuming \\(0\\leq m\\leq k\\), we prove the existence of four polynomials \\(\\Phi_{M+m-i}\\) and \\(\\Psi_{N+k+1}\\), of degrees \\(M+m+1\\) and \\(N+k+i\\) (resp.), such that  \\[ D^{k-m}(\\Phi_{M+m+i}u) =\\Psi_{N+k+i}v(i=0,1), \\]  the \\((k-m)\\)th-derivative, as well as the left-product of a functional by a polynomial, being defined in the usual sense of the theory of distributions. If \\(k-m\\), then \\(u\\) and \\(v\\) are connected by a rational modification. If \\(k=m+1\\), then both \\(u\\) and \\(v\\) are semiclassical linear functionals, which are also connected by a rational modification. 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