quantum Hamiltonian (normal mode, harmonic) (Q6674524): Difference between revisions

Latest revision as of 13:58, 1 December 2025

quantum-mechanical represention of molecular normal modes of vibration within the harmonic approximation

Language	Label	Description	Also known as
English	quantum Hamiltonian (normal mode, harmonic)	quantum-mechanical represention of molecular normal modes of vibration within the harmonic approximation

Statements

instance of

mathematical expression

0 references

in defining formula

N

symbol represents

number of particles

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\hat{H}

symbol represents

Hamiltonian operator

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ω

symbol represents

vibration frequency (harmonic)

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\hat{p}

symbol represents

normal mode momentum (dimensionless)

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\hat{q}

symbol represents

normal coordinate (dimensionless)

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community

MathModDB

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MaRDI profile type

MaRDI formula profile

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defining formula

\hat{H} = \frac{1}{2} \sum_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})

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named after

William Rowan Hamilton

0 references

Sitelinks

Mathematics(1 entry)

mardi Formula:6674524

@@ label / en / label / en @@
-Quantum Hamiltonian (Normal Mode, Harmonic)
+quantum Hamiltonian (normal mode, harmonic)
@@ Property / in defining formula / Property / in defining formula @@
- $p$ 
p
+ $\hat{p}$ 
\hat{p}
@@ Property / in defining formula / Property / in defining formula @@
- $q$ 
q
+ $\hat{q}$ 
\hat{q}
@@ Property / defining formula / Property / defining formula @@
- $\hat{H} = {\frac{1 / 2}{\sum}}_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})$ 
\hat{H}=\frac{1/2}\sum_{i=1}^{3N-6}\omega_i\left(\hat{p}_i^2+\hat{q}_i^2\right)
+ $\hat{H} = \frac{1}{2} \sum_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})$ 
\hat{H}=\frac{1}{2}\sum_{i=1}^{3N-6}\omega_i\left(\hat{p}_i^2+\hat{q}_i^2\right)
@@ Property / named after @@
+William Rowan Hamilton
@@ Property / named after: William Rowan Hamilton / rank @@
+Normal rank

quantum Hamiltonian (normal mode, harmonic) (Q6674524): Difference between revisions

T4schmidt (talk | contribs)

p

p^

q

q^

H^=1/2∑i=13N−6ωi(p^i2+q^i2)

H^=12∑i=13N−6ωi(p^i2+q^i2)

Latest revision as of 13:58, 1 December 2025

Statements

Sitelinks

Mathematics(1 entry)

$p$

$\hat{p}$

$q$

$\hat{q}$

$\hat{H} = {\frac{1 / 2}{\sum}}_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})$

$\hat{H} = \frac{1}{2} \sum_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})$