Equilibrium relationships for non-equilibrium chemical dependencies

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Publication:6219911

arXiv1007.4642MaRDI QIDQ6219911FDOQ6219911

G. S. Yablonskij, D. Constales, Guy B. Marin

Publication date: 27 July 2010

Abstract: In contrast to common opinion, it is shown that equilibrium constants determine the time-dependent behavior of particular ratios of concentrations for any system of reversible first-order reactions. Indeed, some special ratios actually coincide with the equilibrium constant at any moment in time. This is established for batch reactors, and similar relations hold for steady-state plug-flow reactors, replacing astronomic time by residence time. Such relationships can be termed time invariants of chemical kinetics.












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