linear parameter estimation (Elovich isotherm)

Community: MathModDB

computational task

linear task

Available identifiers

MaRDI QIDQ6775815

linear estimation of Elovich adsorption parameters from equilibrium data

Description

This task performs linear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Elovich equilibrium constant and the Elovich maximum adsorption capacity by fitting the linearized form of the Elovich isotherm to measured values of adsorbed amount and equilibrium solution concentration. The linearization expresses the ratio of adsorbed amount to equilibrium concentration in logarithmic form, allowing the model parameters to be obtained from the slope and intercept of a straight-line plot. The resulting parameters describe the surface heterogeneity and the exponential energy distribution assumed by the empirical Elovich model.

List of contained entities

Elovich equilibrium constant
adsorbed solute (equilibrium)
linear Elovich isotherm equation	$\ln \frac{q_e}{c_E}=\ln K_E{q}_m-\frac{q_e}{q_m}$
	$q_e$ represents adsorbed solute (equilibrium)
	$c_E$ represents solute concentration (equilibrium)
	$K_E$ represents Elovich equilibrium constant
	$q_m$ represents maximum monolayer adsorption capacity
maximum monolayer adsorption capacity
solute concentration (equilibrium)

Further items linking to linear parameter estimation (Elovich isotherm)

Item	Property
Elovich isotherm model	used by
nonlinear parameter estimation (Elovich isotherm)	linearized by

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