Bohr Sommerfeld quantisation and molecular potentials

DOI10.1007/S10910-011-9926-0MaRDI QIDQ427443zbMATH OpenOpenAlexFDO

Authors Shayak Bhattacharjee, Jayanta K. Bhattacharjee, Deb Shankar Ray

Publication date 13 June 2012

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1112.4247

zbMATH Keywords

perturbation theoryasymptotic analysisMorse potentialaction integralinterpolation formulaLennard Jones potential

Mathematics Subject Classification ID

Perturbation theories for operators and differential equations in quantum theory (81Q15) Molecular physics (81V55)

Abstract: We use the Bohr Sommerfeld quantization rule along with a perturbative evaluation of the action intergral to find exact energy levels for the P"oschl-Teller potential (both hyperbolic and trigonometric forms), the Morse potential, and the Rosen Morse potential. Combining perturbation theory with the simplest asymptotic evaluation of the action integral allows us to obtain all the energy levels of the Lennard-Jones potential with an accuracy greater than 0.1 per cent and serves to confirm that the perturbation results for P"oschl-Teller and Morse Potentials are exact.

Recommendations

• On Bohr-Sommerfeld-Heisenberg quantization
• Bohr-Sommerfeld quantization rules in the semiclassical limit
• scientific article; zbMATH DE number 4116060
• The exact Bohr-Sommerfeld quantization rule
• Quantum monodromy and Bohr-Sommerfeld rules
• Fermi's ansatz and Bohm's quantum potential
• Extensions of the Bohr–Sommerfeld formula to double-well potentials
• Bohr-Sommerfeld quantization of spin Hamiltonians
• The fine structure of Weber's hydrogen atom: Bohr-Sommerfeld approach
• Bohm's quantum potential as an internal energy

Cites work

• scientific article; zbMATH DE number 3492216 (Why is no real title available?)
• scientific article; zbMATH DE number 5041714 (Why is no real title available?)
• Extensions of the Bohr–Sommerfeld formula to double-well potentials
• Semiclassical approach to Landau levels and Landau level degeneracy using canonical transformations in classical mechanics

Cited in

(8)

• Extending Bohr: Sommerfeld's early atomic theory, 1913-1916
• Sombor Energy and Hückel Rule
• Lindstedt Poincaré technique applied to molecular potentials
• The exact Bohr-Sommerfeld quantization rule
• On Bohr-Sommerfeld-Heisenberg quantization
• Extensions of the Bohr–Sommerfeld formula to double-well potentials
• The fine structure of Weber's hydrogen atom: Bohr-Sommerfeld approach
• Quantum monodromy and Bohr-Sommerfeld rules

This page was built for publication: Bohr Sommerfeld quantisation and molecular potentials

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q427443)