Bond percolation of polymers

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Abstract: We study bond percolation of N non-interacting Gaussian polymers of ell segments on a 2D square lattice of size L with reflecting boundaries. Through simulations, we find the fraction of configurations displaying {em no} connected cluster which span from one edge to the opposite edge. From this fraction, we define a critical segment density hocL(ell) and the associated critical fraction of occupied bonds pcL(ell), so that they can be identified as the percolation threshold in the Loinfty limit. Whereas pcL(ell) is found to decrease monotonically with ell for a wide range of polymer lengths, hocL(ell) is non-monotonic. We give physical arguments for this intriguing behavior in terms of the competing effects of multiple bond occupancies and polymerization.











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